Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin-rhenium carbonyl complex

被引：18
作者：
Aspley, CJ [1 ]
Smith, JRL [1 ]
Perutz, RN [1 ]
机构：
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 14期
关键词：
D O I：
10.1039/a903779i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A systematic synthesis designed to connect a metalloporphyrin to a metal carbonyl moiety is demonstrated through a zinc tetraphenyl porphyrin substituted with Re(CO)(3)(4'-methyl-2,2'-bipyridyl)Br via an amide bond; the emission and excited state absorption spectra are dominated by porphyrin transitions.
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页码：2269 / 2271
页数：3
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