Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin-rhenium carbonyl complex

被引：18

作者：

Aspley, CJ ^{[1
]}

Smith, JRL ^{[1
]}

Perutz, RN ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a903779i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A systematic synthesis designed to connect a metalloporphyrin to a metal carbonyl moiety is demonstrated through a zinc tetraphenyl porphyrin substituted with Re(CO)(3)(4'-methyl-2,2'-bipyridyl)Br via an amide bond; the emission and excited state absorption spectra are dominated by porphyrin transitions.

引用

页码：2269 / 2271

页数：3

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