Experimental and computational approaches for measuring minoxidil solubility in propylene glycol plus water mixtures at different temperatures

被引：8

作者：

Pirhayati, Faezeh H. ^{[1
]}

Mirzaeei, Shahla ^{[1
,2
]}

Rahimpour, Elaheh ^{[3
]}

Mohammadi, Ghobad ^{[1
,2
]}

Martinez, Fleming ^{[4
]}

Taghe, Shiva ^{[1
]}

Jouyban, Abolghasem ^{[5
,6
,7
]}

机构：

[1] Kermanshah Univ Med Sci, Sch Pharm, Pharmaceut Sci Res Ctr, Kermanshah, Iran

[2] Kermanshah Univ Med Sci, Sch Pharm, Nano Drug Delivery Res Ctr, Kermanshah, Iran

[3] Tabriz Univ Med Sci, Drug Appl Res Ctr, Tabriz, Iran

[4] Univ Natl Colombia Sede Bogota, Fac Ciencias, Grp Invest Farmaceut Fisicoquim, Dept Farm, Cra 30 45-03, Bogota, DC, Colombia

[5] Tabriz Univ Med Sci, Pharmaceut Anal Res Ctr, Tabriz, Iran

[6] Tabriz Univ Med Sci, Fac Pharm, Tabriz, Iran

[7] Tabriz Univ Med Sci, Kimia Idea Pardaz Azarbayjan KIPA Sci Based Co, Tabriz, Iran

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 280卷

关键词：

Minoxidil; Propylene glycol; Solubility; Jouyban-Acree model; Thermodynamic properties; Preferential solvation; PREFERENTIAL SOLVATION; COSOLVENT; ETHANOL; METHANOL; SOLVENTS; MODELS; DRUGS;

D O I：

10.1016/j.molliq.2019.01.120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Minoxidil solubility in binary mixtures of propylene glycol + water at different temperatures has been performed by shake-flask method followed by spectrophotometry method. Four cosolvency models including the modified Wilson model, the Yalkowsky model, Jouyban-Acree model and Jouyban-Acree-van't Hoff model were used to correlate the measured solubility data. The correlation and prediction abilities of these models were compared by computing mean relative deviations (MREM. Apparent thermodynamic properties of minoxidil dissolution such as enthalpy, entropy and Gibbs free energy were investigated through van't Hoff and Gibbs equations. Furthermore, preferential solvation parameters of minoxidil were calculated by means of the inverse Kirkwood-Buff integrals. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：334 / 340

页数：7

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