A novel heteropolyanion-based amino-containing cross-linked ionic copolymer catalyst for epoxidation of alkenes with H2O2

被引：35

作者：

Leng, Yan ^{[1
]}

Zhang, Weijie ^{[1
]}

Wang, Jun ^{[2
]}

Jiang, Pingping ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China

[2] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2012年 / 445卷

基金：

中国国家自然科学基金;

关键词：

Heteropolyacid; Cross-linked copolymer; Ionic liquid; Epoxidation of alkenes; Heterogeneous catalysis; TEMPERATURE-RESPONSIVE CATALYST; HYDROGEN-PEROXIDE; HETEROGENEOUS EPOXIDATION; MOLECULAR-OXYGEN; SOLID CATALYSTS; PHASE; POLYOXOMETALATE; LIQUIDS; SYSTEM; ESTERIFICATION;

D O I：

10.1016/j.apcata.2012.08.040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A heteropolyanion-based cross-linked ionic copolymer was prepared by the anion-exchange of a newly task-specific designed amino-containing ionic copolymer with a Keggin heteropolyacid, and characterized by FT-IR, SEM, TG, XRD, UV-vis, ESR, H-1 NMR, and elemental analysis. Its catalytic activity was evaluated in the epoxidation of alkenes with aqueous H2O2. The resultant heteropolyanion-based ionic copolymer is revealed to be a highly efficient heterogeneous catalyst for epoxidation of alkenes with H2O2, adding the advantages of convenient recovery and steady reuse. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：306 / 311

页数：6

共 50 条

[1] Amino-containing cross-linked ionic copolymer-anchored heteropoly acid for solvent-free oxidation of benzyl alcohol with H2O2
Leng, Yan
Wang, Jun
Jiang, Pingping
CATALYSIS COMMUNICATIONS, 2012, 27 : 101 - 104
[2] Amphiphilic phosphotungstate-paired ionic copolymer as a highly efficient catalyst for triphase epoxidation of alkenes with H2O2
Leng, Yan
Wu, Jianghao
Jiang, Pingping
Wang, Jun
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (05) : 1293 - 1300
[3] Silylation of titanium-containing amorphous silica catalyst: Effect on the alkenes epoxidation with H2O2
Capel-Sanchez, M. C.
Campos-Martin, J. M.
Fierro, J. L. G.
CATALYSIS TODAY, 2010, 158 (1-2) : 103 - 108
[4] Heteropolyanion-based polymeric hybrids: highly efficient and recyclable catalysts for oxidation of alcohols with H2O2
Leng, Yan
Liu, Jian
Jiang, Pingping
Wang, Jun
RSC ADVANCES, 2012, 2 (31) : 11653 - 11656
[5] Mo132-Ionic Liquid As An Effective Hybrid Catalyst For Selective Epoxidation of Different Alkenes with H2O2
Farsani, Mostafa Riahi
Yadollahi, Bahram
Taghiyar, Hamid
Moghadam, Ahmad Jamali
CATALYSIS LETTERS, 2025, 155 (02)
[6] Polyoxometalate-based amino-functionalized ionic solid catalysts lead to highly efficient heterogeneous epoxidation of alkenes with H2O2
Leng, Yan
Wang, Jun
Zhu, Dunru
Zhang, Mingjue
Zhao, Pingping
Long, Zhouyang
Huang, Jun
GREEN CHEMISTRY, 2011, 13 (07) : 1636 - 1639
[7] Solvent-free Baeyer-Villiger oxidation with H2O2 as oxidant catalyzed by multi-SO3H functionalized heteropolyanion-based ionic hybrids
Li, Xinzhong
Cao, Rong
Lin, Qi
CATALYSIS COMMUNICATIONS, 2015, 63 : 79 - 83
[8] Heterogeneous epoxidation of alkenes with H2O2 catalyzed by a recyclable organic-inorganic polyoxometalate-based framework catalyst
Haddadi, Hedayat
Hafshejani, Shahrbanou Moradpour
Farsani, Mostafa Riahi
Babahydari, Ali Kazemi
NEW JOURNAL OF CHEMISTRY, 2015, 39 (12) : 9879 - 9885
[9] Peroxopolyoxotungsten-based Ionic Hybrid as a Highly Efficient Recyclable Catalyst for Epoxidation of Vegetable oil with H2O2
Wu, Jianghao
Jiang, Pingping
Qin, Xiaojie
Ye, Yuanyuan
Leng, Yan
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (06): : 1675 - 1680
[10] A Millifluidic Device with Embedded Cross-Linked Enzyme Aggregates for Degradation of H2O2
Jannat, Mahbuba
Yang, Kun-Lin
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (05) : 6768 - 6775

← 1 2 3 4 5 →