Electrochemical conversion of CO2 into dimethyl carbonate in a functionalized ionic liquid

被引：35

作者：

Lu, Bin ^{[1
]}

Wang, Xin ^{[1
]}

Li, Ying ^{[1
]}

Sun, Jia ^{[1
]}

Zhao, Jingxiang ^{[1
]}

Cai, Qinghai ^{[1
]}

机构：

[1] Harbin Normal Univ, Sch Chem & Chem Engn, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Peoples R China

来源：

JOURNAL OF CO2 UTILIZATION | 2013年 / 3-4卷

关键词：

Dimethyl carbonate; Carbon dioxide; Methanol; Amino-functionalized ionic liquids; Electrocatalysis; ORGANIC CARBONATES; DIOXIDE; MILD; ACTIVATION; METHANOL; ELECTROSYNTHESIS; ELECTRODE; BMIMBF4;

D O I：

10.1016/j.jcou.2013.10.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amino-functionalized ionic liquid was synthesized and used as an electrolyte for electrocatalytic activation and conversion of carbon dioxide and methanol into dimethyl carbonate with graphite cathode under ambient conditions. The amino-functionalized ionic liquid was found to be best performance for electrochemical synthesis of dimethyl carbonate from methanol and CO2 in the absence of any other additives due to its effective capture and activation of CO2. The effect of various reaction factors on the synthesis was also discussed. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：98 / 101

页数：4

共 19 条

[1] CO2 capture by a task-specific ionic liquid [J].