Sol-gel synthesis of alumina gel@zeolite X nanocomposites for high performance water defluoridation: batch and column adsorption study

Fluoride content in groundwater above the permissible limit is a major concern worldwide due to its detrimental effects toward human beings. The development of a suitable adsorbent for water defluoridation with high efficiency still remains a great challenge. In this work, an alumina gel@zeolite X nanocomposite was prepared by modification of rice husk ash derived zeolite X with sol-gel derived alumina sol at 70 degrees C/2 h. The crystallinity of zeolite X and the presence of the Si-O-Al vibrational band in the nanocomposite material were confirmed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), respectively. The presence of the adsorbed hydroxyl (OH-) group was confirmed by an X-ray photoelectron spectroscopy (XPS) study indicating the binding energy (BE) at 533.2 eV of the O 1s spectra. During the adsorption process an electrostatic force of attraction and ion exchange mechanism occur between protonated hydroxyl/surface hydroxyl groups and fluoride ions (F-). The nanocomposite with a BET surface area of 257 m(2) g(-1) shows >= 99% fluoride removal for a 1-2 g L-1 adsorbent dose. In the batch study, the Langmuir model was found to be the best fitted adsorption isotherm showing the maximum adsorption capacity of 103.6 mg g(-1) for the adsorbent doses of 0.5 g L-1, while in the column study, the bed depth service time (BDST) model shows an adsorption capacity of 2933.55 mg L-1.