Synthesis and Solution Properties of Carbohydrate-Modified Polysiloxane Bola Surfactants

被引：13

作者：

Zeng, Xiaojun ^{[1
]}

Wang, Hanghang ^{[1
]}

Chen, Yanhong ^{[1
]}

Wang, Liang ^{[2
]}

机构：

[1] Changshu Inst Technol, Sch Chem & Mat Engn, Changshu 215500, Jiangsu, Peoples R China

[2] Yihai Fine Chem Ltd Co, Lianyungang 222000, Jiangsu, Peoples R China

来源：

JOURNAL OF SURFACTANTS AND DETERGENTS | 2015年 / 18卷 / 06期

关键词：

Carbohydrate; Bola surfactant; Polysiloxane; Synthesis; Properties; CRYSTAL PHASE-BEHAVIOR; OLIGO(ETHYLENE OXIDE); SILOXANE SURFACTANTS; AGGREGATION BEHAVIOR; BOLAAMPHIPHILES; NANOPARTICLES; AMPHIPHILES; ADSORPTION; SURFACES; MOIETIES;

D O I：

10.1007/s11743-015-1730-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three carbohydrate-modified polysiloxane bola surfactants (ATPS-GA) were synthesized using a two-step method. Their chemical structures were characterized by infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy (H-1 NMR). Their surface properties and aggregation properties in aqueous solution were determined using surface tension measurements and transmission electron microscopy (TEM). Surface tension measurement results indicated that the three bola surfactants are under 25 mN m(-1), and much lower than those of conventional hydrocarbon bola surfactants due to the siloxane moiety at the end of the hydrophobic chains. TEM analysis results indicated that the ATPS-GA can self-assemble into spherical micelles with a wide range of average diameters from 100 nm to above 600 nm.

引用

页码：1089 / 1094

页数：6

共 43 条

[1] MOLECULAR WEIGHT OF NYLON BY END-GROUP TITRATION [J].

BASU, S .

JOURNAL OF POLYMER SCIENCE, 1950, 5 (06) :735-736

[2] Archaeabacteria bipolar lipid analogues: structure, synthesis and lyotropic properties [J].

Benvegnu, T ;

Brard, M ;

Plusquellec, D .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2004, 8 (06) :469-479

[3] Synthesis of new cellobiose-based glycopolysiloxanes and their use as polymer stabilizers in miniemulsion polymerisation [J].

Berson, Solenn ;

Viet, D. ;

Halila, Sami ;

Driguez, Hugues ;

Fleury, Etienne ;

Hamaide, Thierry .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (17) :1814-1825

[4] Novel sugar bola-amphiphiles with a pseudo macrocyclic structure [J].

Bertho, JN ;

Coue, A ;

Ewing, DF ;

Goodby, JW ;

Letellier, P ;

Mackenzie, G ;

Plusquellec, D .

CARBOHYDRATE RESEARCH, 1997, 300 (04) :341-346

[5]

Black RE, 2001, J AOAC INT, V84, P666

[6] Study on the effect of structure of polydimethylsiloxane grafted with polyethyleneoxide on surface activities [J].

Chung, Dae-Won ;

Lim, Jong Choo .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 336 (1-3) :35-40

[7] Synthesis and physico-chemical characterization of bolaamphiphiles derived from alkenyl D-xylosides [J].

Deleu, Magali ;

Damez, Celine ;

Gatard, Sylvain ;

Nott, Katherine ;

Paquot, Michel ;

Bouquillon, Sandrine .

NEW JOURNAL OF CHEMISTRY, 2011, 35 (10) :2258-2266

[8] Synthesis and preliminary biological studies of hemifluorinated bifunctional bolaamphiphiles designed for gene delivery [J].

Denoyelle, S ;

Polidori, A ;

Brunelle, M ;

Vuillaume, PY ;

Laurent, S ;

ElAzhary, Y ;

Pucci, B .

NEW JOURNAL OF CHEMISTRY, 2006, 30 (04) :629-646

[9] Synthesis, surface and aggregation properties of glucosamide-grafted amphiphilic glycopolysiloxanes [J].

Du, Zhiping ;

Wang, Liang ;

Wang, Guoyong ;

Wang, Shujun .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2011, 381 (1-3) :55-60

[10] Synthesis and aggregation behaviour of two-headed surfactants containing the urocanic acid moiety [J].

Franceschi, S ;

Andreu, V ;

de Viguerie, N ;

Riviere, M ;

Lattes, A ;

Moisand, A .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (03) :225-231

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