Effect of tetrabutylammonium iodide content on PVDF-PMMA polymer blend electrolytes for dye-sensitized solar cells

被引：72

作者：

Theerthagiri, J. ^{[1
]}

Senthil, R. A. ^{[1
]}

Buraidah, M. H. ^{[2
]}

Madhavan, J. ^{[1
]}

Arof, A. K. ^{[2
]}

机构：

[1] Thiruvalluvar Univ, Dept Chem, Solar Energy Lab, Vellore 632115, Tamil Nadu, India

[2] Univ Malaya, Dept Phys, Ctr Ion, Kuala Lumpur 50603, Malaysia

来源：

IONICS | 2015年 / 21卷 / 10期

关键词：

Tetrabutylammonium iodide; PVDF-PMMA blend; Polymer electrolytes; Ionic conductivity; Dye-sensitized solar cells; PERFORMANCE; CONDUCTIVITY; MEMBRANES; SALT;

D O I：

10.1007/s11581-015-1464-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of tetrabutylammonium iodide on the polyvinylidene fluoride-poly(methyl methacrylate)-ethylene carbonate (PVDF-PMMA-EC)-I-2 polymer blend electrolytes was investigated and optimized for use in a dye-sensitized solar cell. The different weight ratios (50, 60, 70, and 80 %) of tetrabutylammonium iodide (TBAI)-added PVDF-PMMA-EC-I-2 polymer electrolytes were prepared. The prepared solid polymer blend electrolytes were characterized by using various techniques such as Fourier transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC), and electrochemical impedance spectroscopy (EIS). The FT-IR spectra revealed the interaction among all composition of polymer electrolytes. The influence of TBAI salt on the ionic conductivity of polymer electrolytes was studied using electrochemical impedance spectroscopy. The polymer electrolyte containing 60 % of TBAI in PVDF-PMMA-EC-I-2 showed the highest room temperature conductivity of 5.10 x 10(-3) S cm(-1). The fabricated DSSC using PVDF-PMMA-EC-I-2 polymer electrolytes with 60 % of TBAI showed the best performance with a short-circuit current density of 8.0 mA cm(-2), open-circuit voltage of 0.66 V, fill factor of 0.65, and the overall power conversion efficiency of 3.45 % under an illumination of 100 mW cm(-2). Hence, the weight content of organic iodide salt in polymer electrolytes influences the overall performance of dye-sensitized solar cells.

引用

页码：2889 / 2896

页数：8