Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Based on Glutaric Acid and Triazole

被引：0
|
作者：
Liu, Guang-Xiang [1 ]
机构：
[1] Nanjing Xiaozhuang Univ, Sch Biochem & Environm Engn, Nanjing 211171, Jiangsu, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2013年 / 24卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Cadmium(II) coordination polymer; Glutaric acid; 1,2,4-triazole; Crystal structure; Luminescence; MAGNETIC-PROPERTIES; HYDROTHERMAL SYNTHESIS; RETICULAR CHEMISTRY; OPEN FRAMEWORK; CU-II; LIGANDS; NLO; 1,2,4-TRIAZOLE; TOPOLOGIES; TRINUCLEAR;
D O I：
10.1007/s10876-013-0574-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer, [Cd-7(mu (3)-O)(2)(glut)(2)(Hglut)(2)(trz)(4)](n) (1) (H(2)glut = glutaric acid and Htrz = 1,2,4-triazole), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a fairly complicated three-dimensional (3D) (3,3,6,10)-connected framework constructed from two-dimensional (2D) infinite [Cd-7(mu (3)-O)(2)(glut)(4)(Hglut)(2)](n) layers and [Cd(trz)(4)](2-) units. Moreover, the thermal stability and photoluminescent properties of 1 were also investigated.
引用
收藏
页码：935 / 944
页数：10
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