Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Based on Glutaric Acid and Triazole

被引：0

作者：

Liu, Guang-Xiang ^{[1
]}

机构：

[1] Nanjing Xiaozhuang Univ, Sch Biochem & Environm Engn, Nanjing 211171, Jiangsu, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2013年 / 24卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Cadmium(II) coordination polymer; Glutaric acid; 1,2,4-triazole; Crystal structure; Luminescence; MAGNETIC-PROPERTIES; HYDROTHERMAL SYNTHESIS; RETICULAR CHEMISTRY; OPEN FRAMEWORK; CU-II; LIGANDS; NLO; 1,2,4-TRIAZOLE; TOPOLOGIES; TRINUCLEAR;

D O I：

10.1007/s10876-013-0574-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer, [Cd-7(mu (3)-O)(2)(glut)(2)(Hglut)(2)(trz)(4)](n) (1) (H(2)glut = glutaric acid and Htrz = 1,2,4-triazole), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a fairly complicated three-dimensional (3D) (3,3,6,10)-connected framework constructed from two-dimensional (2D) infinite [Cd-7(mu (3)-O)(2)(glut)(4)(Hglut)(2)](n) layers and [Cd(trz)(4)](2-) units. Moreover, the thermal stability and photoluminescent properties of 1 were also investigated.

引用

页码：935 / 944

页数：10

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