Aziridination of alkenes with N-substituted hydrazines mediated by iodobenzene diacetate

被引：85
|
作者：
Li, JY
Liang, JL
Chan, PWH
Che, CM
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Synth, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China
[2] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[3] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Open Lab Chem Biol, Hong Kong, Hong Kong, Peoples R China
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 12期
关键词：
D O I：
10.1016/j.tetlet.2004.01.127
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aziridination of a variety of alkenes with N-substituted hydrazines mediated by iodobenzene diacetate under mild conditions (K2CO3, CH2Cl2) and ambient temperature were achieved in good to excellent yields (up to 99%), and conversions. The practicality and simplicity of this C-N bond formation protocol was exemplified by its application to the aziridination of cholesteryl acetate in a stereoselective manner. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2685 / 2688
页数：4
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