Hydroxylated PBDEs and brominated phenolic compounds in particulate matters emitted during recycling of waste printed circuit boards in a typical e-waste workshop of South China

被引:0
作者
Ren, Zhaofang [1 ,2 ]
Bi, Xinhui [1 ]
Huang, Bo [1 ,2 ]
Liu, Ming [1 ,2 ]
Sheng, Guoying [1 ]
Fu, Jiamo [1 ,3 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Utilizat & Protect Environ, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
[3] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
关键词
Hydroxylated polybrominated diphenyl ethers; Bromophenols; Printed circuit boards; E-waste; POPs; POLYBROMINATED DIPHENYL ETHERS; DIBENZO-P-DIOXINS; FLAME RETARDANTS; BALTIC SEA; OH-PBDES; BLOOD-PLASMA; EXPOSED RATS; IN-VITRO; METABOLITES; IDENTIFICATION;
D O I
10.1016/j.envpol.2013.01.034
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The hydroxylated PBDEs (OH-PBDEs) and brominated phenolic compounds in aerosol samples from a printed circuit boards recycling workshop were characterized. The results show that OH-PBDEs, which are naturally occurring compounds or metabolism of PBDEs, could also be emitted from the e-waste recycling. Five OH-PBDEs, several unidentified mono-OH-PBDE and di-OH-PBDE congeners were detected. The concentration of Sigma OH-PBDEs was 1.74-4.22 ng m(-3) (average of 2.66 ng m(-3)), with 6-OH-BDE-47 (0.329 ng m(-3)) as the most abundant identified congener. The total concentration of di- to tri-brominated phenols (BPs) was 18.8-32.0 ng m(-3) (average of 26.3 ng m(-3)) with 2,4,6-triBP as the most abundant congener. These findings suggest that the recycling of printed circuit boards represent a strong source of OH-PBDEs and BPs to the atmosphere. Additionally, some phenolic compounds including brominated bisphenol A, hydroxylated polybrominated biphenyl species and etc. were also identified. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:71 / 77
页数:7
相关论文
共 48 条
[1]   On-site and off-site atmospheric PBDEs in an electronic dismantling workshop in south China: Gas-particle partitioning and human exposure assessment [J].
An, Taicheng ;
Zhang, Delin ;
Li, Guiying ;
Mai, Bixian ;
Fu, Jiamo .
ENVIRONMENTAL POLLUTION, 2011, 159 (12) :3529-3535
[2]   An experimental investigation of tetrabromobisphenol A decomposition pathways [J].
Barontini, F ;
Cozzani, V ;
Marsanich, K ;
Raffa, V ;
Petarca, L .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2004, 72 (01) :41-53
[3]   The major components of particles emitted during recycling of waste printed circuit boards in a typical e-waste workshop of South China [J].
Bi, Xinhui ;
Simoneit, Bernd R. T. ;
Wang, ZhenZhen ;
Wang, Xinming ;
Sheng, Guoying ;
Fu, Jiamo .
ATMOSPHERIC ENVIRONMENT, 2010, 44 (35) :4440-4445
[4]   Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis [J].
Blazsó, M ;
Czégény, Z ;
Csoma, C .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2002, 64 (02) :249-261
[5]   Inhibition of human placental aromatase activity by hydroxylated polybrominated diphenyl ethers (OH-PBDEs) [J].
Canton, Rocio F. ;
Scholten, Deborah E. A. ;
Marsh, Goran ;
De Jong, Paul C. ;
Van den Berg, Martin .
TOXICOLOGY AND APPLIED PHARMACOLOGY, 2008, 227 (01) :68-75
[6]   Simultaneous quantification of multiple classes of phenolic compounds in blood plasma by liquid chromatography-electrospray tandem mass spectrometry [J].
Chang, Hong ;
Wan, Yi ;
Naile, Jonathan ;
Zhang, Xiaowei ;
Wiseman, Steve ;
Hecker, Markus ;
Lam, Michael H. W. ;
Giesy, John P. ;
Jones, Paul D. .
JOURNAL OF CHROMATOGRAPHY A, 2010, 1217 (04) :506-513
[7]   Distribution of PBDEs in air particles from an electronic waste recycling site compared with Guangzhou and Hong Kong, South China [J].
Deng, W. J. ;
Zheng, J. S. ;
Bi, X. H. ;
Fu, J. M. ;
Wong, M. H. .
ENVIRONMENT INTERNATIONAL, 2007, 33 (08) :1063-1069
[8]   Hydroxylation increases the neurotoxic potential of BDE-47 to affect exocytosis and calcium homeostasis in PC12 cells [J].
Dingemans, Milou M. L. ;
de Groot, Aart ;
van Kleef, Regina G. D. M. ;
Bergman, Ake ;
van den Berg, Martin ;
Vijverberg, Henk P. M. ;
Westerink, Remco H. S. .
ENVIRONMENTAL HEALTH PERSPECTIVES, 2008, 116 (05) :637-643
[9]   Photochemical Formation of Brominated Dioxins and Other Products of Concern from Hydroxylated Polybrominated Diphenyl Ethers (OH-PBDEs) [J].
Erickson, Paul R. ;
Grandbois, Matthew ;
Arnold, William A. ;
McNeill, Kristopher .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2012, 46 (15) :8174-8180
[10]   Surface-mediated formation of polybrominated dibenzo-p-dioxins and dibenzofurans from the high-temperature pyrolysis of 2-bromophenol on a CuO/silica surface [J].
Evans, CS ;
Dellinger, B .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (13) :4857-4863