Oxygenation of organic sulfides catalyzed by simple Fe(III) salts

被引：20

作者：

Villalobos, Leslie ^{[1
]}

Ren, Tong ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 28卷

关键词：

Catalytic oxygenation; Organic sulfide; Fe(III) halides; Hydrogen peroxide; HYDROGEN-PEROXIDE; OXIDATION; SELECTIVITY; EPOXIDATION; SULFOXIDES; H2O2;

D O I：

10.1016/j.inoche.2012.11.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organic sulfide oxygenation by hydrogen peroxide (H2O2) was effectively accomplished by using iron(III) chloride or iron(III) bromide as the catalyst. The distribution of products between sulfoxide and sulfone is strongly solvent-dependent, and a 100% selectivity for sulfoxide was achieved with FeCl3 in a 1:1 methanol/water mixture. (C) 2012 Elsevier B.V. All rights reserved.

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页码：52 / 54

页数：3

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