New imine-phosphine palladium complexes catalyze copolymerization of CO-ethylene and CO-norbornylene and provide well-characterized stepwise insertion intermediates of various unsaturated substrates

被引：103
作者：
Reddy, KR [1 ]
Chen, CL [1 ]
Liu, YH [1 ]
Peng, SM [1 ]
Chen, JT [1 ]
Liu, ST [1 ]
机构：
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 14期
关键词：
D O I：
10.1021/om990222+
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New imine-phosphine palladium complexes [Pd(P-N)(CH3)(CH3CN)](BF4) (P-N = o-(diphenylphosphino)-N-benzaldimine derivatives) are synthesized and are found to be active for copolymerization of CO-ethylene and CO-norbornylene, respectively. Stepwise addition of carbon monoxide and various olefins into the new complexes is investigated.
引用
收藏
页码：2574 / 2576
页数：3
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