Capturing electrochemical transformations by tip-enhanced Raman spectroscopy

被引：21
作者：
Touzalin, Thomas [1 ]
Joiret, Suzanne [1 ]
Maisonhaute, Emmanuel [1 ]
Lucas, Ivan T. [1 ]
机构：
[1] UPMC Univ Paris 06, Sorbonne Univ, Lab Interfaces & Syst Electrochim, UMR 8235, F-75005 Paris, France
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2017年 / 6卷 / 01期
关键词：
SOLID-ELECTROLYTE INTERPHASE; IR NEAR-FIELD; SINGLE-MOLECULE; IN-SITU; NANOSCALE; SURFACE; MICROSCOPY; AU(111); SILVER; WATER;
D O I：
10.1016/j.coelec.2017.10.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Through the characterization of functional nanomaterials or of molecular architectures under operating conditions (in situ, operando), new insights in their working mechanism will be accessible. In this context, tip-enhanced Raman spectroscopy (TERS) which enables the extraction of precise chemical signatures at the nanoscale represents a great alternative to ultra-high vacuum analytical techniques. This review compiles the recent advances in in situ TERS characterizations and focuses on the strong potential of TERS to characterize the electrochemical processes taking place at the electrode/electrolyte interface.
引用
收藏
页码：46 / 52
页数：7
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