Organometallic chemistry directed towards organic synthesis - Our own story

被引：0

作者：

Ma, SM ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 11期

关键词：

organometallic chemistry directed towards organic synthesis (OMCOS); Pd; Cu; cyclization; lithiation; coupling; bicyclic carbopalladation;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper summarizes Dr. Shengming Ma's major research achievement since 1997, which includes: (1) the cyclization reaction of functionalized allenes, such as 1,2-allenyl carboxylic acids, amides, ketones, 2,3allenyl alcohols or 2-(2',3'-allenyl)malonates providing new entries for the efficient synthesis of heterocycles and carbocycles; (2) monolithiation of 1-aryl-1-alkynes under the catalysis of 1.5 mol% HgCl2, and the subsequent tunable regioselective coupling reaction with organic halides; (3) bicyclic carbopalladation of 1, 1-dibromo-1-alkenes providing a new and efficient entry for the construction of fused bicycles.

引用

页码：833 / 841

页数：9

共 30 条

[21] Bicyclic carbopalladation reaction with two gem-reaction centers.: Efficient construction of fused bicyclic skeletons
Ma, SM
Xu, B
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (25) : 9156 - 9157
[22] Ma SM, 2000, SYNTHESIS-STUTTGART, P139
[23] Pd(0)/Ag+-cocatalyzed cyclization reaction of 1,2-allenic carboxylic acids with aryl/alkenyl halides.: An efficient synthesis of butenolides
Ma, SM
Shi, ZJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (18) : 6387 - 6389
[24] Efficient synthesis of 4-halo-4-penten-2-ones and 3-halo-3-butenoic acids/esters via hydrohalogenation reaction of 3,4-pentadien-2-one and 2,3-butadienoic acid methyl ester
Ma, SM
Shi, ZJ
Li, LT
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (13) : 4522 - 4523
[25] Hydrohalogenation reaction of 1,2-allenyl ketones revisited.: Efficient and highly stereoselective synthesis of β,γ-unsaturated β-haloketones
Ma, SM
Li, LT
Xie, HX
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (14) : 5325 - 5328
[26] Pd(0)-catalyzed insertion-cyclization reaction of 2,3-allenols with aryl or alkenyl halides.: Diastereoselective synthesis of highly optically active trans-2,3-disubstituted vinylic oxiranes
Ma, SM
Zhao, SM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (34) : 7943 - 7944
[27] Pd0-catalyzed cyclization reaction of aryl or alk-1-enyl halides with 1,2-dienyl ketones:: a general and efficient synthesis of polysubstituted furans
Ma, SM
Zhang, JL
[J]. CHEMICAL COMMUNICATIONS, 2000, (02) : 117 - 118
[28] Ma SM, 1999, CHINESE J CHEM, V17, P531
[29] Studies on the oxidative addition reaction of 1,1-dibromo-1-alkenes, α-dehalopalladation, and the intramolecular bis(carbopalladation) reaction of alkenes.: An efficient entry to fused bicycles
Ma, SM
Xu, B
Ni, BK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (25) : 8532 - 8543
[30] MA SM, 2001, METAL INVOLVED MODER

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