Organometallic chemistry directed towards organic synthesis - Our own story

被引：0

作者：

Ma, SM ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 11期

关键词：

organometallic chemistry directed towards organic synthesis (OMCOS); Pd; Cu; cyclization; lithiation; coupling; bicyclic carbopalladation;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper summarizes Dr. Shengming Ma's major research achievement since 1997, which includes: (1) the cyclization reaction of functionalized allenes, such as 1,2-allenyl carboxylic acids, amides, ketones, 2,3allenyl alcohols or 2-(2',3'-allenyl)malonates providing new entries for the efficient synthesis of heterocycles and carbocycles; (2) monolithiation of 1-aryl-1-alkynes under the catalysis of 1.5 mol% HgCl2, and the subsequent tunable regioselective coupling reaction with organic halides; (3) bicyclic carbopalladation of 1, 1-dibromo-1-alkenes providing a new and efficient entry for the construction of fused bicycles.

引用

页码：833 / 841

页数：9

共 30 条

[1] Ma SM, 2000, EUR J ORG CHEM, V2000, P1939
[2] HgCl2-catalyzed benzylation of 1-aryl-1-propynes
Ma, SM
Wang, LS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10) : 3497 - 3498
[3] Chemistry of 1,2-allenyl/propargyl metal species. A personal account
Ma, SM
Zhang, AB
[J]. PURE AND APPLIED CHEMISTRY, 2001, 73 (02) : 337 - 341
[4] Hydrohalogenation reaction of electron-deficient allenes
Ma, SM
Li, LT
Wei, Q
Xie, HX
Wang, GW
Shi, ZJ
Zhang, JL
[J]. PURE AND APPLIED CHEMISTRY, 2000, 72 (09) : 1739 - 1743
[5] Enantioselective synthesis of β-arylbutenolides via palladium(0) catalysed asymmetric coupling cyclisation reaction of racemic allenic carboxylic acids with aryl iodides
Ma, SM
Shi, ZJ
Wu, SL
[J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (02) : 193 - 195
[6] CuBr2-mediated direct aqueous bromolactonization of 2,3-allenoates.: An efficient access to β-bromobutenolides
Ma, SM
Wu, SL
[J]. TETRAHEDRON LETTERS, 2001, 42 (24) : 4075 - 4077
[7] Novel CuX2-mediated cyclization of acid-base salts of (L)-cinchonidine or (D)-/(L)-α-methylbenzylamine and 2,3-allenoic acids in an aqueous medium.: An efficient entry to optically active β-halobutenolides
Ma, SM
Wu, SL
[J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 441 - 442
[8] Unexpected facile sequential halolactamization-hydroxylation of 2,3-allenamides with CuX2 for the efficient synthesis of 4-halo-5-hydroxypyrrol-2(5H)-ones
Ma, SM
Xie, HX
[J]. ORGANIC LETTERS, 2000, 2 (24) : 3801 - 3803
[9] Efficient synthesis of 4-(2′-alkenyl)-2,5-dihydrofurans via PdCl2-catalyzed coupling-cyclization reaction of 2,3-allenols with allylic halides
Ma, SM
Gao, WZ
[J]. TETRAHEDRON LETTERS, 2000, 41 (46) : 8933 - 8936
[10] Unusual regioselectivity of Pd(0)-catalyzed coupling reaction of electron-deficient alkenyl halides with allenic/propargylic zinc reagents. Highly selective synthesis of 6-phenylhex-5-yn-2(or 3)-enoates/enitrile and 4-phenyl-6-substituted-hexa-2,4,5-trienoates
Ma, SM
Zhang, AB
Yu, YH
Xia, W
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (08) : 2287 - 2291

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