Selective metal substitution for the preparation of heterobimetallic microporous coordination polymers

被引：92
作者：
Caskey, Stephen R.
Matzger, Adam J. [1 ]
机构：
[1] Univ Michigan, Dept Chem & Macromol Sci, Ann Arbor, MI 48109 USA
来源：
INORGANIC CHEMISTRY | 2008年 / 47卷 / 18期
关键词：
D O I：
10.1021/ic8007427
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4 MOF-39, and a Zn-BTEC MCP are reported.
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收藏
页码：7942 / 7944
页数：3
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