Cyclodextrin-centred star polymers synthesized via a combination of thiol-ene click and ring opening polymerization

被引：77
|
作者：
Zhang, Qiang [1 ]
Li, Guang-Zhao [1 ]
Becer, C. Remzi [1 ]
Haddleton, David M. [1 ]
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 65期
关键词：
CHEMISTRY; CHAIN; POLY(EPSILON-CAPROLACTONE); CLUSTERS; BEHAVIOR; CORES; 7-ARM;
D O I：
10.1039/c2cc33742h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of cyclodextrin-centred star polymers via thiol-ene addition of per-6-thio-beta-cyclodextrin (CD-(SH)(7)) with vinyl terminated polymers is described. The obtained thiol-ene product was employed as an initiator for ring opening polymerization (ROP) of epsilon-caprolactone (epsilon-CL).
引用
收藏
页码：8063 / 8065
页数：3
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