Hydride vapor phase epitaxy (HVPE) is used nowadays for the growth of new III-V semiconductors (GaN, InGaN...), as well as for the selective epitaxy of III-V layers on patterned III-V [E.R. Messmer et al., Materials Science and Engineering B51 (1998), pp. 238-241] or silicon [O. Parillaud, E. Gil-Lafon, B. Gerard, P. Etienne, D. Pribat, Appl. Phys. Lett. 68 (1996), pp. 2654-2656] substrates. It has already been demonstrated that InAs/InP strained quantum wells [H. Banvillet, E. Gil-Lafon, R. Cadoret, P. Disseix, K. Ferdjani, A. Vasson, A.M. Vasson, A. Tabata, T. Benyattou, G. Guillot, J. Appl. Phys. 70 (3) 1991, pp. 1638-1641.] and InGaAs/InP quantum wells [N. Piffault, E. Gil, J. Leymarie, S.A. Clark, M. Anderson, R. Cadoret, A. Vasson, A.M. Vasson, J. Crystal Growth 135 (1994), pp. 11-22.] could be achieved by HVPE. We will present here the study of the growth of InAsP/InP strained quantum wells by HVPE. Relaxed InAsP layers were first grown in order to determine the composition of the alloys. Single quantum wells and multi-quantum well structures were then achieved. Photoluminescence analysis of the samples have shown the high quality of the InAsP/InP quantum wells. The feasibility of low dimensionality structures using HVPE process was then demonstrated, with an accurate control of the thickness and the composition of InAsP/InP quantum wells. (C) 1999 Elsevier Science B.V. All rights reserved.