LCST-Type Phase Behavior Induced by Pillar[5]arene/Ionic Liquid Host-Guest Complexation

被引：121

作者：

Dong, Shengyi ^{[1
]}

Zheng, Bo ^{[1
]}

Yao, Yong ^{[1
]}

Han, Chengyou ^{[1
]}

Yuan, Jiayin ^{[2
]}

Antonietti, Markus ^{[2
]}

Huang, Feihe ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

[2] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 47期

基金：

中国国家自然科学基金;

关键词：

pillararenes; lower critical solution temperature; ionic liquids; host-guest systems; supramolecular chemistry; IONIC LIQUIDS; LINEAR-POLYMERS; ORGANIZATION; NANOPARTICLES; HYDROGELS; CAPSULES; RELEASE; MONOMER;

D O I：

10.1002/adma.201303652

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The host-guest complex of dipropoxypillar[5]arene and an ionic liquid 1,3-dimethylimidazolium iodide is found to exhibit a lower critical solution temperature (LCST)-type phase transition in chloroform. This LCST-type phase behavior can be conveniently modulated by experimental parameters and can be easily combined with the ionic liquid for potential application in product and educt separation. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6864 / 6867

页数：4

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