LCST-Type Phase Behavior Induced by Pillar[5]arene/Ionic Liquid Host-Guest Complexation

被引：120
作者：
Dong, Shengyi [1 ]
Zheng, Bo [1 ]
Yao, Yong [1 ]
Han, Chengyou [1 ]
Yuan, Jiayin [2 ]
Antonietti, Markus [2 ]
Huang, Feihe [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 47期
基金：
中国国家自然科学基金;
关键词：
pillararenes; lower critical solution temperature; ionic liquids; host-guest systems; supramolecular chemistry; IONIC LIQUIDS; LINEAR-POLYMERS; ORGANIZATION; NANOPARTICLES; HYDROGELS; CAPSULES; RELEASE; MONOMER;
D O I：
10.1002/adma.201303652
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The host-guest complex of dipropoxypillar[5]arene and an ionic liquid 1,3-dimethylimidazolium iodide is found to exhibit a lower critical solution temperature (LCST)-type phase transition in chloroform. This LCST-type phase behavior can be conveniently modulated by experimental parameters and can be easily combined with the ionic liquid for potential application in product and educt separation. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6864 / 6867
页数：4
相关论文
共 51 条
  • [1] Pseudopolyanions based on poly(NIPAAM-co-β-cyclodextrin methacrylate) and ionic liquids
    Amajjahe, Sadik
    Choi, Soowhan
    Munteanu, Maricica
    Ritter, Helmut
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) : 3435 - 3437
  • [2] Supramolecular controlled pseudo-LCST effects of cyclodextrin-complexed poly(ionic liquids)
    Amajjahe, Sadik
    Ritter, Helmut
    [J]. MACROMOLECULES, 2008, 41 (09) : 3250 - 3253
  • [3] Nonpolymeric Thermosensitive Supramolecules
    Betancourt, Jose E.
    Rivera, Jose M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) : 16666 - +
  • [4] Multi-shell Soft Nanotubes from Cyclic Peptide Templates
    Chapman, Robert
    Jolliffe, Katrina A.
    Perrier, Sebastien
    [J]. ADVANCED MATERIALS, 2013, 25 (08) : 1170 - 1172
  • [5] A [2]Rotaxane Flip Switch Driven by Coordination Geometry
    Davidson, Gregory J. E.
    Sharma, Sapna
    Loeb, Stephen J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (29) : 4938 - 4942
  • [6] Thermosensitive micelles formed from a small-molecule amphiphile: switchable LCST and potential application in cloud point separation
    Ding, Yan
    Wang, Zhiqiang
    Zhang, Xi
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (49) : 5580 - 5582
  • [7] A Dual-Responsive Supramolecular Polymer Gel Formed by Crown Ether Based Molecular Recognition
    Dong, Shengyi
    Luo, Yan
    Yan, Xuzhou
    Zheng, Bo
    Ding, Xia
    Yu, Yihua
    Ma, Zhi
    Zhao, Qiaoling
    Huang, Feihe
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (08) : 1905 - 1909
  • [8] Novel [2]pseudorotaxanes constructed by self-assembly of bis-urea-functionalized pillar[5]arene and linear alkyl dicarboxylates
    Duan, Qunpeng
    Xia, Wei
    Hu, Xiaoyu
    Ni, Mengfei
    Jiang, Juli
    Lin, Chen
    Pan, Yi
    Wang, Leyong
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (68) : 8532 - 8534
  • [9] Halogen Bonding inside a Molecular Container
    El-Sheshtawy, Hamdy S.
    Bassil, Bassem S.
    Assaf, Khaleel I.
    Kortz, Ulrich
    Nau, Werner M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (48) : 19935 - 19941
  • [10] Reversible Immobilization onto PEG-based Emulsion-templated Porous Polymers by Co-assembly of Stimuli Responsive Polymers
    Fernandez-Trillo, Francisco
    van Hest, Jon C. M.
    Thies, Jens C.
    Michon, Thierry
    Weberskirch, Ralf
    Cameron, Neil R.
    [J]. ADVANCED MATERIALS, 2009, 21 (01) : 55 - 59
123456