Preparation and Characterization of Manganese Schiff Base Complexes as Models for PSII

被引：0

作者：

Matsushita, Takayuki ^{[1
]}

Imagawa, Hitoshi ^{[1
]}

Asada, Hideyuki ^{[1
]}

Kasuno, Megumi ^{[1
]}

Fujiwara, Manabu ^{[1
]}

机构：

[1] Ryukoku Univ, Fac Sci & Technol, Dept Chem Mat, Otsu, Shiga 5202194, Japan

来源：

EUROBIC 9: PROCEEDINGS OF THE 9TH EUROPEAN BIOLOGICAL INORGANIC CHEMISTRY CONFERENCE | 2008年

关键词：

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

To mimic O(2) generation in PSII we have synthesized dinuclear manganese complexes with Schiff bases, which were obtained by the condensation between triethylenetetramine and salicylaldehyde derivatives. Moreover, novel dinucleating ligands, which were derived from 5,5'-methylene-bis-salicylaldehyde and alkylesters of 1 : 1 condensation product of 5-carboxysalicylaldehyde and ethylenediamine, and their manganese(III) complexes have been prepared. These manganese complexes have been identified by elemental analysis and physico-chemical measurements. These complexes have been found to react with water to generate O(2) in low yields.

引用

页码：151 / 155

页数：5

共 5 条

[1] Structures of dichloromanganese(IV) complexes with bidentate and tetradentate Schiff base ligands [J].