Novel rosette-shaped CdS microparticle with high surface area fabricated by lyotropic liquid crystal templating

被引:7
作者
Im, SJ
Chae, WS
Lee, SW
Kim, YR [1 ]
机构
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[2] Yonsei Univ, Photon Appl Funct Mol Res Lab, Seoul 120749, South Korea
关键词
semiconductors; chalcogenides; nanostructures; chemical synthesis; optical properties;
D O I
10.1016/j.materresbull.2005.09.023
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Semiconductor US microparticle covered with wrinkle-like nanotexture was prepared under ambient condition by using the lyotropic liquid crystal mesophase as a structural template. The prepared US microparticle resembles a rosette shape with a diameter of 0.5-1.5 mu m and the wrinkle-like nanotexture on its surface. This rosette-shaped US consists of small nanocrystals with a diameter of similar to 4 nm, and the nanocrystal building block has the zinc-blende crystal structure. The characteristic band-to-band absorption and near band-edge emission are observed in this unique semiconductor particle. Nitrogen gas physisorption measurement reveals that the material has the high BET surface area of 38 m(2) g(-1)and nanoporous nature. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:899 / 904
页数:6
相关论文
共 23 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   CdS mineralization of hexagonal, lamellar, and cubic lyotropic liquid crystals [J].
Braun, PV ;
Stupp, SI .
MATERIALS RESEARCH BULLETIN, 1999, 34 (03) :463-469
[3]   Emission characteristics of CdS nanoparticles induced by confinement within MCM-41 nanotubes [J].
Chae, WS ;
Ko, JH ;
Hwang, IW ;
Kim, YR .
CHEMICAL PHYSICS LETTERS, 2002, 365 (1-2) :49-56
[4]   In situ synthesis of mesoporous CdS nanoparticles in ternary cubic phase lyotropic liquid crysta [J].
Huang, NM ;
Kan, CS ;
Radiman, S .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2003, 76 (04) :555-559
[5]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[6]   Simultaneous in situ formation of ZnS nanowires in a liquid crystal template by γ-irradiation [J].
Jiang, X ;
Xie, Y ;
Lu, J ;
Zhu, LY ;
He, W ;
Qian, YT .
CHEMISTRY OF MATERIALS, 2001, 13 (04) :1213-1218
[7]   Origin of hysteresis of gas adsorption in disordered porous media: Lattice gas model versus percolation theory [J].
Kikkinides, ES ;
Kainourgiakis, ME ;
Stubos, AK .
LANGMUIR, 2003, 19 (08) :3338-3344
[8]  
Klug H.P., 1974, XRAY DIFFRACTION PRO, V2nd, P992
[9]   Preparation of porous silica-pillared layered phase:: Simultaneous intercalation of amine-tetraethylorthosilicate into the H+-magadiite and intragallery amine-catalyzed hydrolysis of tetraethylorthosilicate [J].
Kwon, OY ;
Shin, HS ;
Choi, SW .
CHEMISTRY OF MATERIALS, 2000, 12 (05) :1273-1278
[10]   Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions [J].
Lee, K ;
Kim, YH ;
Han, SB ;
Kang, HK ;
Park, S ;
Seo, WS ;
Park, JT ;
Kim, B ;
Chang, SB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (23) :6844-6845