Effect of adding method of Cr on microstructure and properties of WC-9Ni-2Cr cemented carbides
被引:19
作者:
Shi Kai-hua
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Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Shi Kai-hua
[1
]
Zhou Ke-chao
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机构:
Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Zhou Ke-chao
[1
]
Li Zhi-you
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机构:
Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Li Zhi-you
[1
]
Zan Xiu-qi
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机构:
Zi Gong Cemented Carbide Corp Ltd, Zigong 643011, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Zan Xiu-qi
[2
]
Xu Shang-zhi
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机构:
Zi Gong Cemented Carbide Corp Ltd, Zigong 643011, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Xu Shang-zhi
[2
]
Min Zhao-yu
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机构:
Zi Gong Cemented Carbide Corp Ltd, Zigong 643011, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Min Zhao-yu
[2
]
机构:
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Zi Gong Cemented Carbide Corp Ltd, Zigong 643011, Peoples R China
The WC-9Ni-2Cr cemented carbides were prepared by ball milling method and low pressure sintering. The microstructure and properties of the cemented carbides were then investigated using scanning electron microscopy, mechanical property tester and immersion corrosion tests. The results showed that the adding method of Cr significantly influenced the microstructure and properties of the WC-9Ni-2Cr cemented carbides. Cemented carbides with Cr added in the form of chromium carbide (Cr3C2) were characterized by carburizing and showed a relative lower density, while the addition of metallic chromium and nichrome (Ni-18Cr) resulted in the formation of (W,Cr)C phase and a decrease in the bending strength. However, no defects were found in the microstructure of the cemented carbides in which Cr was added via Cr-Cr3C2 composite powder. Furthermore, cemented carbides prepared with nichrome powder and metallic Cr powder exhibited a higher immersion corrosion resistance in neutral tap water after soaking six times according to BS:6920:2000. (C) 2012 Elsevier Ltd. All rights reserved.