The one-component plasma: a conceptual approach

被引:19
作者
Tamashiro, MN [1 ]
Levin, Y [1 ]
Barbosa, MC [1 ]
机构
[1] Univ Fed Rio Grande Sul, Inst Fis, BR-91501970 Porto Alegre, RS, Brazil
来源
PHYSICA A | 1999年 / 268卷 / 1-2期
关键词
one-component plasma; electrolytes; structure factors; Debye-Huckel theory;
D O I
10.1016/S0378-4371(99)00013-8
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The one-component plasma (OCP) represents the simplest statistical mechanical model of a Coulomb system. For this reason, it has been extensively studied over the last 40 years. The advent of the integral equations has resulted in a dramatic improvement in our ability to carry out numerical calculations, but came at the expense of a physical insight gained in a simpler analytic theory. In this paper we present an extension of the Debye-Huckel (DPI) theory to the OCP. The theory allows for analytic calculations of all the thermodynamic functions, as well as the structure factor. The theory explicitly satisfies the Stillinger-Lovett and, for small couplings, the compressibility sum rules, implying its internal self consistency. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:24 / 49
页数:26
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