Thiocyanate-free cyclometalated ruthenium sensitizers for solar cells based on heteroaromatic-substituted 2-arylpyridines

被引：38

作者：

Abbotto, Alessandro ^{[1
,3
]}

Coluccini, Carmine ^{[1
]}

Dell'Orto, Elisa ^{[1
]}

Manfredi, Norberto ^{[1
]}

Trifiletti, Vanira ^{[1
]}

Salamone, Matteo M. ^{[1
]}

Ruffo, Riccardo ^{[1
]}

Acciarri, Maurizio ^{[1
]}

Colombo, Alessia ^{[2
]}

Dragonetti, Claudia ^{[2
]}

Ordanini, Stefania ^{[2
]}

Roberto, Dominique ^{[2
,3
]}

Valore, Adriana ^{[3
]}

机构：

[1] Milano Bicocca Solar Energy Res Ctr, MIB Solar, Dept Mat Sci, I-20125 Milan, Italy

[2] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit La, UdR Milano, INSTM, Milan, Italy

[3] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 38期

关键词：

IRIDIUM COMPLEXES; LIGHT; EFFICIENCY; COORDINATION; CONVERSION; DYNAMICS;

D O I：

10.1039/c2dt31551c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first examples of thiocyanate-free thiophene-substituted Ru(II) cyclometalated complexes, based on thiophene-derived 2-(2,4-difluorophenyl)pyridine ligands, are presented and investigated as photosensitizers in DSCs. Upon thiophene substitution the complexes presented enhanced optical properties compared to the reference dye with no thiophene substitution. DSCs based on the dithienyl-derived dye showed power conversion efficiencies up to 5.7%, more than twice that containing the complex without the thiophene substitution.

引用

页码：11731 / 11738

页数：8

共 46 条

[21] Photochemistry and photophysics of coordination compounds: Iridium [J].

Flamigni, Lucia ;

Barbieri, Andrea ;

Sabatini, Cristiana ;

Ventura, Barbara ;

Barigelletti, Francesco .

PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS II, 2007, 281 :143-203

[22] Recent Advances in Sensitized Mesoscopic Solar Cells [J].

Graetzel, Michael .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1788-1798

[23] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[24] Dye-Sensitized Solar Cells [J].

Hagfeldt, Anders ;

Boschloo, Gerrit ;

Sun, Licheng ;

Kloo, Lars ;

Pettersson, Henrik .

CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663

[25] Device Physics of Dye Solar Cells [J].

Halme, Janne ;

Vahermaa, Paula ;

Miettunen, Kati ;

Lund, Peter .

ADVANCED MATERIALS, 2010, 22 (35) :E210-E234

[26] Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J].

Ito, Seigo ;

Murakami, Takurou N. ;

Comte, Pascal ;

Liska, Paul ;

Graetzel, Carole ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

THIN SOLID FILMS, 2008, 516 (14) :4613-4619

[27] Structural Modification of Organic Dyes for Efficient Coadsorbent-Free Dye-Sensitized Solar Cells [J].

Jiang, Xiao ;

Marinado, Tannia ;

Gabrielsson, Erik ;

Hagberg, Daniel P. ;

Sun, Licheng ;

Hagfeldt, Anders .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (06) :2799-2805

[28] A New Class of Cyclometalated Ruthenium Sensitizers of the Type CNN for Efficient Dye-Sensitized Solar Cells [J].

Kim, Jeum-Jong ;

Choi, Hyunbong ;

Paek, Sanghyun ;

Kim, Chulwoo ;

Lim, Kimin ;

Ju, Myung-Jong ;

Kang, Hong Seok ;

Kang, Moon-Sung ;

Ko, Jaejung .

INORGANIC CHEMISTRY, 2011, 50 (22) :11340-11347

[29] Synthesis, structures and electrochemical properties of ruthenium (II) complexes bearing bidentate 1,8-naphthyridine and terpyridine analogous (N,N,C)-tridentate ligands [J].

Koizumi, TA ;

Tomon, T ;

Tanaka, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (19) :4272-4279

[30] Electron Transfer Dynamics in Dye-Sensitized Solar Cells [J].

Listorti, Andrea ;

O'Regan, Brian ;

Durrant, James R. .

CHEMISTRY OF MATERIALS, 2011, 23 (15) :3381-3399

← 1 2 3 4 5 →