Thiocyanate-free cyclometalated ruthenium sensitizers for solar cells based on heteroaromatic-substituted 2-arylpyridines

被引：38

作者：

Abbotto, Alessandro ^{[1
,3
]}

Coluccini, Carmine ^{[1
]}

Dell'Orto, Elisa ^{[1
]}

Manfredi, Norberto ^{[1
]}

Trifiletti, Vanira ^{[1
]}

Salamone, Matteo M. ^{[1
]}

Ruffo, Riccardo ^{[1
]}

Acciarri, Maurizio ^{[1
]}

Colombo, Alessia ^{[2
]}

Dragonetti, Claudia ^{[2
]}

Ordanini, Stefania ^{[2
]}

Roberto, Dominique ^{[2
,3
]}

Valore, Adriana ^{[3
]}

机构：

[1] Milano Bicocca Solar Energy Res Ctr, MIB Solar, Dept Mat Sci, I-20125 Milan, Italy

[2] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit La, UdR Milano, INSTM, Milan, Italy

[3] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 38期

关键词：

IRIDIUM COMPLEXES; LIGHT; EFFICIENCY; COORDINATION; CONVERSION; DYNAMICS;

D O I：

10.1039/c2dt31551c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first examples of thiocyanate-free thiophene-substituted Ru(II) cyclometalated complexes, based on thiophene-derived 2-(2,4-difluorophenyl)pyridine ligands, are presented and investigated as photosensitizers in DSCs. Upon thiophene substitution the complexes presented enhanced optical properties compared to the reference dye with no thiophene substitution. DSCs based on the dithienyl-derived dye showed power conversion efficiencies up to 5.7%, more than twice that containing the complex without the thiophene substitution.

引用

页码：11731 / 11738

页数：8

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