Effect of Mo addition on the phase stability of β-Nb5Si3 phase

被引:31
作者
Li, W [1 ]
Yang, HB [1 ]
Shan, AD [1 ]
Zhang, LT [1 ]
Wu, JS [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Key Lab Minist Educ High Temp Mat & Test, Shanghai 200030, Peoples R China
基金
中国国家自然科学基金;
关键词
intermetallics; miscellaneous (not otherwise listed; including model systems); bonding; crystallography; phase transformations (crystallographic aspects; kinetics and mechanisms);
D O I
10.1016/j.intermet.2005.07.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Effect of Mo addition on phase stability of beta-Nb5Si3 in NbSi2/Nb5Si3 in situ composites has been investigated using X-ray diffraction (XRD). The preferential occupancy of the Mo atoms in the beta-Nb5Si3 structure was investigated with the Rietveld profile technique. It is suggested that Mo addition stabilizes the beta-Nb5Si3 phase. The results were explained on the basis of selective substitution of Mo atoms in beta-Nb5Si3. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:392 / 395
页数:4
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