Synthesis and crystal structure of dinuclear copper complex [Cu(CH2O(C6H4)N=C(C6H4)O)(Py)]2

被引：0

作者：

Niu, DZ ^{[1
]}

Mu, LL

Lu, ZS

Wang, YC

Chen, JT

机构：

[1] Xuzhou Normal Univ, Dept Chem, Jiangsu 221009, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 01期

关键词：

copper (II); 2-aminobenzoic alcohol; salicylaldehyde; pyridine; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Complex [Cu2L2(Py)(2)] (H2L=2-aminobenzoic alcohol condensation salicylaldehyde) was obtained. A single-crystal X-ray study shows that the complex is a binuclear compound (Cu2C38H32N4O4). The coordination geometry about each copper atom is best described as a distorted square pyramid. The compound [Cu2L2(Py)(2)] belongs to monoclinic system with space group P2(1), lattice constants: a = 10.3881 (1), b = 17.9724(1), c = 17.5800(2) Angstrom, beta=90.4880(1)degrees, V= 3282.05(5) Angstrom(3), Z= 4, M-r =735.75, D-c=1.489 g/cm(3), mu= 1.344mm(-1), F(000) = 1512, R=0.0519, wR=0.1092 for 6725 reflections with I >2sigma(I). The distances between Cu(II) and O atoms are range from 1.898(6) to 1.976(5)Angstrom, between Cu(II) and N atoms are range from 1.990(6) to 2.369(7)Angstrom. The Cu(1)-Cu(2) bond length is 3.024(4) Angstrom.

引用

页码：55 / 59

页数：5

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