The reaction of 1-ethylthio-3-iminopyrrolizines with hydroxylamine. A new synthesis of 3-aminoisoxazoles

被引：7

作者：

Sobenina, LN ^{[1
]}

Drichkov, VN ^{[1
]}

Mikhaleva, AI ^{[1
]}

Petrova, OV ^{[1
]}

Ushakov, IA ^{[1
]}

Trofimov, BA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, 1 Favorsky Str, Irkutsk 664033, Russia

来源：

ARKIVOC | 2005年

关键词：

1-ethylthio-3-iminopyrrolizine-2-carbonitriles; 1-ethylthio-3-iminopyrrolizine-2-carboxamides; hydroxylamine; 3-aminoisoxazoles; exchange;

D O I：

10.3998/ark.5550190.0006.704

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 1-ethylthio-3-iminopyrrolizine-2-carbonitriles with hydroxylamine leads to 1-hydroxylamino-3-iminopyrrolizine-2-carbonitriles, whereas 1-ethylthio-3-iminopyrrolizine-2carboxamides and hydroxylamines give 3-aminoisoxazoles, as major products. The exchange of the ethylthio group for the hydroxylamine moiety is a side reaction of this approach.

引用

页码：28 / 35

页数：8

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