CVD-synthesis of multiwall carbon nanotubes over potassium-doped supported catalysts

被引:24
作者
Balogh, Zoltan [1 ]
Halasi, Gyula [1 ]
Korbely, Barbara [1 ]
Hernadi, Klara [1 ]
机构
[1] Univ Szeged, Dept Appl & Environm Chem, H-6720 Szeged, Hungary
关键词
carbon nanotube; CVD method; K-doped; combinatorial synthesis; TEM;
D O I
10.1016/j.apcata.2008.04.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mono-(Co) and bimetallic (Fe-Co) catalysts supported by either 13X zeolite or CaCO3 were doped with potassium and tested in carbon nanotube (CNT) production using the chemical vapor deposition (CVD) method. In order to increase comparability, the evaluation of the performance of the catalysts a combinatorial arrangement was also used. Catalyst samples were characterized by carbon deposit and carbon yield values. For qualitative characterization, products were investigated by transmission electron microscopy. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:191 / 197
页数:7
相关论文
共 19 条
  • [1] CVD synthesis of high-purity multiwalled carbon nanotubes using CaCO3 catalyst support for large-scale production
    Couteau, E
    Hernadi, K
    Seo, JW
    Thiên-Nga, L
    Mikó, C
    Gaál, R
    Forró, L
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 378 (1-2) : 9 - 17
  • [2] LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES
    EBBESEN, TW
    AJAYAN, PM
    [J]. NATURE, 1992, 358 (6383) : 220 - 222
  • [3] Combinatorial synthesis of carbon nanotubes by the catalytic chemical vapor deposition method
    Fási, A
    Zsák, P
    Pálinkó, I
    Hernádi, K
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 2006, 87 (02): : 349 - 357
  • [4] CATALYTIC GROWTH OF SINGLE-WALLED NANOTUBES BY LASER VAPORIZATION
    GUO, T
    NIKOLAEV, P
    THESS, A
    COLBERT, DT
    SMALLEY, RE
    [J]. CHEMICAL PHYSICS LETTERS, 1995, 243 (1-2) : 49 - 54
  • [5] Catalytic synthesis of carbon nanotubes using zeolite support
    Hernadi, K
    Fonseca, A
    Nagy, JB
    Bernaerts, D
    Fudala, A
    Lucas, AA
    [J]. ZEOLITES, 1996, 17 (5-6): : 416 - 423
  • [6] Catalytic synthesis of multiwall carbon nanotubes from methylacetylene
    Hernadi, K
    [J]. CHEMICAL PHYSICS LETTERS, 2002, 363 (1-2) : 169 - 174
  • [7] HELICAL MICROTUBULES OF GRAPHITIC CARBON
    IIJIMA, S
    [J]. NATURE, 1991, 354 (6348) : 56 - 58
  • [8] THE STUDY OF CARBON NANOTUBULES PRODUCED BY CATALYTIC METHOD
    IVANOV, V
    NAGY, JB
    LAMBIN, P
    LUCAS, A
    ZHANG, XB
    ZHANG, XF
    BERNAERTS, D
    VANTENDELOO, G
    AMELINCKX, S
    VANLANDUYT, J
    [J]. CHEMICAL PHYSICS LETTERS, 1994, 223 (04) : 329 - 335
  • [9] Carbon nanotube field-effect transistors with integrated ohmic contacts and high-k gate dielectrics
    Javey, A
    Guo, J
    Farmer, DB
    Wang, Q
    Wang, DW
    Gordon, RG
    Lundstrom, M
    Dai, HJ
    [J]. NANO LETTERS, 2004, 4 (03) : 447 - 450
  • [10] XPS characterisation of catalysts during production of multiwalled carbon nanotubes
    Kónya, Z
    Kiss, J
    Oszkó, A
    Siska, A
    Kiricsi, I
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (01) : 155 - 158