Tishchenko reactions and Oppenauer oxidation reactions of aldehydes promoted by diisobutylaluminum hydride

被引：24

作者：

Hon, YS ^{[1
]}

Chang, CP

Wong, YC

机构：

[1] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan

[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 16期

关键词：

Tishchenko reaction; Oppenauer oxidation; alpha-silyloxyaldehyde; alpha-silyloxyketone;

D O I：

10.1016/j.tetlet.2004.02.145

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aliphatic aldehydes react with catalytic amount of Dibal-H in n-pentane to give the corresponding Tishchenko products in good to excellent yields. Contrary, alpha-silyloxyaldehydes give alpha-silyloxyketones via Oppenauer oxidation under similar condition. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3313 / 3315

页数：3

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