Visible-light-driven photoelectrochemical and photocatalytic performances of Cr-doped SrTiO3/TiO2 heterostructured nanotube arrays

被引:91
作者
Jiao, Zhengbo [1 ,2 ]
Chen, Tao [1 ,2 ]
Xiong, Jinyan [1 ,2 ]
Wang, Teng [1 ,2 ]
Lu, Gongxuan [1 ,2 ]
Ye, Jinhua [3 ,4 ]
Bi, Yingpu [1 ,2 ]
机构
[1] Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou 730000, Peoples R China
[3] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050047, Japan
[4] Natl Inst Mat Sci, Res Unit Environm Remediat Mat, Tsukuba, Ibaraki 3050047, Japan
基金
中国国家自然科学基金;
关键词
TITANIA NANOTUBES; TIO2;
D O I
10.1038/srep02720
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Well-aligned TiO2 nanotube arrays have become of increasing significance because of their unique highly ordered array structure, high specific surface area, unidirectional charge transfer and transportation features. However, their poor visible light utilization as well as the high recombination rate of photoexcited electron-hole pairs greatly limited their practical applications. Herein, we demonstrate the fabrication of visible-light-responsive heterostructured Cr-doped SrTiO3/TiO2 nanotube arrays by a simple hydrothermal method, which facilitate efficient charge separation and thus improve the photoelectrochemical as well as photocatalytic performances.
引用
收藏
页数:6
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共 25 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Nanocrystalline mesoporous strontium titanate as photoelectrode material for photosensitized solar devices:: Increasing photovoltage through flatband potential engineering [J].
Burnside, S ;
Moser, JE ;
Brooks, K ;
Grätzel, M ;
Cahen, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (43) :9328-9332
[3]   A Facile in Situ Hydrothermal Method to SrTiO3/TiO2 Nanofiber Heterostructures with High Photocatalytic Activity [J].
Cao, Tieping ;
Li, Yuejun ;
Wang, Changhua ;
Shao, Changlu ;
Liu, Yichun .
LANGMUIR, 2011, 27 (06) :2946-2952
[4]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[5]   Semiconductor-based Photocatalytic Hydrogen Generation [J].
Chen, Xiaobo ;
Shen, Shaohua ;
Guo, Liejin ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2010, 110 (11) :6503-6570
[6]   SrTiO3 Recombination-Inhibiting Barrier Layer for Type II Dye-Sensitized Solar Cells [J].
Hod, Idan ;
Shalom, Menny ;
Tachan, Zion ;
Ruhle, Sven ;
Zaban, Arie .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (21) :10015-10018
[7]   Rh-Doped SrTiO3 Photocatalyst Electrode Showing Cathodic Photocurrent for Water Splitting under Visible-Light Irradiation [J].
Iwashina, Katsuya ;
Kudo, Akihiko .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (34) :13272-13275
[8]   Tunable Photocatalytic Selectivity of Hollow TiO2 Microspheres Composed of Anatase Polyhedra with Exposed {001} Facets [J].
Liu, Shengwei ;
Yu, Jiaguo ;
Jaroniec, Mietek .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) :11914-11916
[9]   TiO2 Nanotubes: Synthesis and Applications [J].
Roy, Poulomi ;
Berger, Steffen ;
Schmuki, Patrik .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (13) :2904-2939
[10]   Synthesis and UV-visible-light photoactivity of noble-metal-SrTiO3 composites [J].
Subramanian, V ;
Roeder, RK ;
Wolf, EE .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2187-2193