The Experimental Study of Temperature Dependence of Binary Diffusion Coefficients of Gases at Different Pressures

被引：4

作者：

Bogatyrev, A. F. ^{[1
]}

Nezovitina, M. A. ^{[1
]}

机构：

[1] Natl Res Univ, Moscow Power Engn Inst, Smolensk Branch, Smolensk 214013, Russia

来源：

INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2013年 / 34卷 / 11期

关键词：

Binary diffusion coefficients; Binary gaseous systems; Elementary kinetic theory; Experiment; Temperature dependence;

D O I：

10.1007/s10765-013-1539-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

An experimental study of the temperature dependence of the binary diffusion coefficients (BDCs) was conducted for five binary mixtures of gases: , and . Measurements were carried out with the use of a steady-flow method in the temperature range from 250 K to 900 K and the pressure range from 0.1 MPa to 15 MPa. The determination of the BDCs is based on analysis of the volume fraction of the diffusing gas in the gas flow. The experimental data were compared with the results of calculations by the proposed formula evaluated within the framework of the elementary kinetic theory. The obtained results exhibit considerably good agreement with the experimental data within the experimental error. The results of investigations of the temperature dependence of the BDCs show that this dependence can be fitted with a power law only at atmospheric pressure.

引用

页码：2065 / 2075

页数：11

共 22 条

[11]

Kosov N.D., 1965, J TECH PHYS, V35, P2120

[12]

Kosov N.D., 1970, THERMOPHYSICAL PROPE, P197

[13]

Kosov N.D., 1982, THERMOPHYSICAL PROPE

[14]

Kosov N.D., 1982, THERMOPHYSICAL PARAM, P4

[15]

Kosov N.D., 1981, PHYSICS, V2, P23

[16] Measurement of Binary Diffusion Coefficients for Neon-Argon Gas Mixtures Using a Loschmidt Cell Combined with Holographic Interferometry [J].

Kugler, T. ;

Jaeger, B. ;

Bich, E. ;

Rausch, M. H. ;

Froeba, A. P. .

INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2013, 34 (01) :47-63

[17] AN ELEMENTARY THEORY OF THERMAL AND PRESSURE DIFFUSION IN GASEOUS BINARY AND COMPLEX MIXTURES [J].

LARANJEIRA, MF .

PHYSICA, 1960, 26 (06) :409-416

[18]

Nanis J., 1965, REV SCI INSTRUM, V36, P673

[19]

Seleznev V.D., 1982, THERMOPHYSICAL PROPE

[20]

Solonicyn B.P., 1978, APPL THEORETICAL PHY, P50

← 1 2 3 →