Symmetry of high-piezoelectric Pb-based complex perovskites at the morphotropic phase boundary:: I.: Neutron diffraction study on Pb(Zn1/3Nb2/3)O3-9%PbTiO3

被引：67
作者：
Uesu, Y
Matsuda, M
Yamada, Y
Fujishiro, K
Cox, DE
Noheda, B
Shirane, G
机构：
[1] Waseda Univ, Dept Phys, Shinjuku Ku, Tokyo 1698555, Japan
[2] Brookhaven Natl Lab, Dept Phys, Upton, NY 11973 USA
[3] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[4] Japan Atom Energy Res Inst, Asc Sci Res Ctr, Tokai, Ibaraki 3191195, Japan
[5] Waseda Univ, Adv Res Inst, Shinjuku Ku, Tokyo 1698555, Japan
来源：
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN | 2002年 / 71卷 / 03期
关键词：
piezoelectricity; ferroelectricity; morphotropic phase boundary; neutron diffraction; Pb (Zn1/3Nb2/3)O-3/9%PbTiO3;
D O I：
10.1143/JPSJ.71.960
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The symmetry was examined using neutron diffraction method on Pb(Zn1/3Nb2/3)O-3-9%PbTiO3 (PZN/9PT) which has a composition at the morphotropic phase boundary between Pb(Zn1/3Nb2/3)O-3 and PbTiO3. The results were compared with those of other specimens with same composition but with different prehistory. The equilibrium state of all examined specimens is not the mixture of rhombohedral and tetragonal phases of the end members but exists in a new polarization rotation line Mc# (orthorhombic-monoclinic line). Among examined specimens, one exhibited tetragonal symmetry at room temperature but recovered monoclinic phase after a cooling and heating cycle.
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页码：960 / 965
页数：6
相关论文
共 16 条
  • [1] Finite-temperature properties of Pb(Zr1-xTix)O3 alloys from first principles
    Bellaiche, L
    García, A
    Vanderbilt, D
    [J]. PHYSICAL REVIEW LETTERS, 2000, 84 (23) : 5427 - 5430
  • [2] COX DE, 2001, IN PRESS APPL PHYS L
  • [3] Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics
    Fu, HX
    Cohen, RE
    [J]. NATURE, 2000, 403 (6767) : 281 - 283
  • [4] Origin of the high piezoelectric response in PbZr1-xTixO3
    Guo, R
    Cross, LE
    Park, SE
    Noheda, B
    Cox, DE
    Shirane, G
    [J]. PHYSICAL REVIEW LETTERS, 2000, 84 (23) : 5423 - 5426
  • [5] Jaffe B., 1971, PIEZOELECTRIC CERAMI
  • [6] PHASE-TRANSITIONS IN THE PB(ZN1/3NB2/3)O3-PBTIO3 SYSTEM
    KUWATA, J
    UCHINO, K
    NOMURA, S
    [J]. FERROELECTRICS, 1981, 37 (1-4) : 579 - 582
  • [7] The role of processing variables in the flux growth of lead zinc niobate-lead titanate relaxor ferroelectric single crystals
    Mulvihill, ML
    Park, SE
    Risch, G
    Li, ZA
    Uchino, K
    Shrout, TR
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (07): : 3984 - 3990
  • [8] A monoclinic ferroelectric phase in the Pb(Zr1-xTix)O3 solid solution
    Noheda, B
    Cox, DE
    Shirane, G
    Gonzalo, JA
    Cross, LE
    Park, SE
    [J]. APPLIED PHYSICS LETTERS, 1999, 74 (14) : 2059 - 2061
  • [9] Stability of the monoclinic phase in the ferroelectric perovskite PbZr1-xTixO3
    Noheda, B
    Cox, DE
    Shirane, G
    Guo, R
    Jones, B
    Cross, LE
    [J]. PHYSICAL REVIEW B, 2001, 63 (01)
  • [10] Polarization rotation via a monoclinic phase in the piezoelectric 92% PbZn1/3Nb2/3O3-8% PbTiO3
    Noheda, B
    Cox, DE
    Shirane, G
    Park, SE
    Cross, LE
    Zhong, Z
    [J]. PHYSICAL REVIEW LETTERS, 2001, 86 (17) : 3891 - 3894
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