Deposition of a TMDSO-Based Film by a Non-Equilibrium Atmospheric Pressure DC Plasma Jet

被引:24
作者
Deng, Xiaolong [1 ,2 ]
Nikiforov, Anton Yu [1 ,3 ]
De Geyter, Nathalie [1 ]
Morent, Rino [1 ]
Leys, Christophe [1 ]
机构
[1] Univ Ghent, Dept Appl Phys, B-9000 Ghent, Belgium
[2] Natl Univ Def Technol, Coll Optoelect Sci & Engn, Changsha 410073, Hunan, Peoples R China
[3] Inst Solut Chem RAS, Ivanovo 153045, Russia
基金
欧洲研究理事会;
关键词
DC discharges; deposition; plasma jet; FT-IR; XPS; DIELECTRIC BARRIER DISCHARGE; COATINGS; POLYMERIZATION;
D O I
10.1002/ppap.201200166
中图分类号
O59 [应用物理学];
学科分类号
摘要
This work deals with the deposition of thin films using an atmospheric pressure direct current nitrogen plasma jet with tetramethyldisiloxane as precursor. The effect of O-2 flow and plasma discharge power on film deposition rate and film chemical characteristics is investigated in detail by surface profilometry, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. It is found that a higher deposition rate is obtained at higher oxygen flow rates and higher discharge powers. Increasing discharge power shows a certain amount of capability to transfer low oxygen content bonds to high oxygen content bonds. Organic films can be deposited in a pure nitrogen atmosphere. The film chemical composition can be tuned to a more inorganic structure by admixture of O-2 leading to an increase in SiO4 units at high oxygen flow rates.
引用
收藏
页码:641 / 648
页数:8
相关论文
共 27 条
[1]   Kinetics of RPECVD Organosilicon Polymer Post-treatment in a N2/O2 Microwave Plasma Remote Afterglow [J].
Abou Rich, Sami ;
Mille, Vianney ;
Vivien, Celine ;
Godey, Sylvie ;
Supiot, Philippe .
PLASMA PROCESSES AND POLYMERS, 2010, 7 (9-10) :775-784
[2]   Non-equilibrium constricted dc glow discharge in N2 flow at atmospheric pressure: stable and unstable regimes [J].
Akishev, Yu ;
Grushin, M. ;
Karalnik, V. ;
Petryakov, A. ;
Trushkin, N. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (07)
[3]   A study of HMDSO/O2 plasma deposits using a high-sensitivity and -energy resolution XPS instrument:: curve fitting of the Si 2p core level [J].
Alexander, MR ;
Short, RD ;
Jones, FR ;
Michaeli, W ;
Blomfield, CJ .
APPLIED SURFACE SCIENCE, 1999, 137 (1-4) :179-183
[4]  
[Anonymous], 1980, Infrared Characteristic Group Frequencies
[5]  
[Anonymous], INGENIERIA
[6]   Nonequilibrium Atmospheric Plasma Deposition [J].
Belmonte, T. ;
Henrion, G. ;
Gries, T. .
JOURNAL OF THERMAL SPRAY TECHNOLOGY, 2011, 20 (04) :744-759
[7]   Characterization of an atmospheric pressure dc plasma jet [J].
Bibinov, N. ;
Dudek, D. ;
Awakowicz, P. ;
Engemann, J. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (23) :7372-7378
[8]   Plasma polymerisation of siloxanes at atmospheric pressure [J].
De Geyter, N. ;
Morent, R. ;
Van Vlierberghe, S. ;
Dubruel, P. ;
Leys, C. ;
Schacht, E. .
SURFACE ENGINEERING, 2011, 27 (08) :627-633
[9]   Permeation mechanisms of pulsed microwave plasma deposited silicon oxide films for food packaging applications [J].
Deilmann, Michael ;
Grabowski, Mirko ;
Theiss, Sebastian ;
Bibinov, Nikita ;
Awakowicz, Peter .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (13)
[10]   Effect of growth parameters on single crystal diamond deposition by DC Arc Plasma Jet CVD [J].
Hei, Lifu ;
Liu, Jie ;
Lu, Fanxiu ;
Li, Chengming ;
Song, Jianhua ;
Chen, Guangchao .
MECHATRONICS AND INTELLIGENT MATERIALS II, PTS 1-6, 2012, 490-495 :3094-+