Synthesis and (3+2) cycloaddition reactions of N,N E1 and C,N-cyclic azomethine imines

被引：25

作者：

Belskaya, Nataliya P. ^{[1
]}

Bakulev, Vasiliy A. ^{[1
]}

Fan, Zhijin ^{[2
,3
]}

机构：

[1] Ural Fed Univ, 19 Mira St, Ekaterinburg 620002, Russia

[2] Nankai Univ, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China

[3] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2016年 / 52卷 / 09期

基金：

中国国家自然科学基金; 俄罗斯基础研究基金会;

关键词：

C; N-cyclic azomethine imines; N; N '-cyclic azomethine imines; pyrazolo[5,1-a]isoquinolines; pyrazolo[1,2-a]pyrazoles; (3+2) cycloaddition; ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; DINITROGEN-FUSED HETEROCYCLES; ALPHA; BETA-UNSATURATED ALDEHYDES; IONIC LIQUIDS; ALKENE AMINOCARBONYLATION; ALKYNE CYCLOADDITIONS; NITROGEN-HETEROCYCLES; REGIO; ACCESS; ANNULATION;

D O I：

10.1007/s10593-016-1943-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review considers new methods for the synthesis of N,N E-1- and C,N-cyclic azomethine imines, as well as the most characteristic of their transformations - (3+2)-dipolar cycloaddition reactions. Particular attention was focused on the issues of regio- and stereoselectivity, the effects of the structure of starting materials, solvents, and catalysts on the reaction direction and yields of cycloadducts. The review covers literature data about the chemistry of cyclic azomethine imines published over the previous 10 years. There are 71 references given.

引用

页码：627 / 636

页数：10

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