Comment on "Kinetics and thermodynamics of Eu(III) adsorption onto synthetic monoclinic pyrrhotite" by Y. Zhu et al., Journal of Molecular Liquids, 218 (2016), 565-570

被引:0
作者
Finck, Nicolas [1 ]
Luetzenkirchen, Johannes [1 ]
Hanna, Khalil [2 ]
Rabung, Thomas [1 ]
机构
[1] Karlsruhe Inst Technol, Inst Nucl Waste Disposal INE, POB 3640, D-76021 Karlsruhe, Germany
[2] Ecole Natl Super Chim Rennes, CNRS, UMR 6226, 11 Allee Beaulieu,CS 50837, F-35708 Rennes 7, France
关键词
Europium; Pyrrhotite; Adsorption; Complexation; Thermodynamics; SORPTION; PYRITE;
D O I
10.1016/j.molliq.2016.10.094
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The paper of Zhu et al. [1] is of great interest, since it reported adsorption data of Eu(III) onto pyrrhotite, an uninvestigated solid surface to date. We are of the opinion that the system is of relevance in the context of nuclear waste disposal in deep repositories. In the study, Eu(III) is used as an analogue for trivalent actinides and pyrrhotite might be a relevant mineral under reducing conditions. Unfortunately, for readers interested in using the uptake data for developing a surface complexation model, some crucial information concerning experimental conditions is missing and some statements in the text require some clarification. We aim here to raise some relevant questions in a constructive way, to achieve a correct understanding of this interesting data. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:1022 / 1024
页数:3
相关论文
共 14 条
  • [1] Surface charge development on transition metal sulfides: An electrokinetic study
    Bebie, J
    Schoonen, MAA
    Fuhrmann, M
    Strongin, DR
    [J]. GEOCHIMICA ET COSMOCHIMICA ACTA, 1998, 62 (04) : 633 - 642
  • [2] A review on pyrrhotite oxidation
    Belzile, N
    Chen, YW
    Cai, MF
    Li, YR
    [J]. JOURNAL OF GEOCHEMICAL EXPLORATION, 2004, 84 (02) : 65 - 76
  • [3] In situ high-temperature phase transformation studies on pyrite
    Bhargava, S. K.
    Garg, A.
    Subasinghe, N. D.
    [J]. FUEL, 2009, 88 (06) : 988 - 993
  • [4] SPECIAL ISSUE - NATURAL ANALOGS TO THE CONDITIONS AROUND A FINAL REPOSITORY FOR HIGH-LEVEL RADIOACTIVE-WASTE - INTRODUCTION AND SUMMARY OF THE WORKSHOP
    CHAPMAN, NA
    SMELLIE, JAT
    [J]. CHEMICAL GEOLOGY, 1986, 55 (3-4) : 167 - 173
  • [5] DEKKERS MJ, 1994, GEOCHIM COSMOCHIM AC, V58, P4147
  • [6] Lipincott E. R., 1958, J RES NBS, V61, P61
  • [7] Potentiometric Titrations as a Tool for Surface Charge Determination
    Luetzenkirchen, Johannes
    Preocanin, Tajana
    Kovacevic, Davor
    Tomisic, Vladislav
    Lovgren, Lars
    Kallay, Nikola
    [J]. CROATICA CHEMICA ACTA, 2012, 85 (04) : 391 - 417
  • [8] Lurzenkirchen J., 1998, J COLLOID INTERF SCI, V202, P212
  • [9] Ionic strength effects on cation sorption to oxides: Macroscopic observations and their significance in microscopic interpretation
    Lutzenkirchen, J
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 195 (01) : 149 - 155
  • [10] X-RAY PHOTOELECTRON AND AUGER ELECTRON-SPECTROSCOPY OF AIR-OXIDIZED PYRRHOTITE - DISTRIBUTION OF OXIDIZED SPECIES WITH DEPTH
    MYCROFT, JR
    NESBITT, HW
    PRATT, AR
    [J]. GEOCHIMICA ET COSMOCHIMICA ACTA, 1995, 59 (04) : 721 - 733