Synthesis and characterization of Cu3N nanoparticles using pyrrole-2-carbaldpropyliminato Cu(II) complex and Cu(NO3)2 as single-source precursors: the search for an ideal precursor

Herein, we report the synthesis and characterization of Cu3N nanocrystals using two single-source precursors, bis(pyrrole-2-carbalpropyliminato) Cu(II) (PPC) and Cu(NO3)(2)center dot 3H(2)O. The optical and structural properties were investigated and the suitability of the two precursors was studied in terms of producing good quality Cu3N nanocrystals without the detection of Cu or oxidation to CuO. Both precursors resulted in crystalline Cu3N with an anti-ReO3 cubic structure with no presence of copper impurities, however, peaks due to excess capping agent were detected by XRD and confirmed with XPS. The PPC complex resulted in spherical nanocrystals whilst the copper nitrate resulted in nanocubes. The band gaps were in the visible region with the copper nitrate nanocrystals slightly red shifted from the PPC derived particles due to larger crystal sizes. The emission spectra were blue-shifted from the absorption band edges hence indicating an up-conversion process.