"Reactive" probe for hydrogen sulfite: Good ratiometric response and bioimaging application

被引：98

作者：

Cheng, Xiaohong ^{[1
]}

Jia, Huizhen ^{[1
]}

Feng, Jun ^{[1
]}

Qin, Jingui ^{[1
]}

Li, Zhen ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2013年 / 184卷

关键词：

Ratiometric probe; Hydrogen sulfite; Intramolecular charge transfer; Selectivity; Bioimaging application; ANION RECEPTORS; FLUORESCENT CHEMOSENSORS; MOLECULAR RECOGNITION; SELECTIVE DETECTION; BISULFITE ADDUCTS; LIVING CELLS; GUANIDINIUM; BINDING; DESIGN; SENSOR;

D O I：

10.1016/j.snb.2013.04.070

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

4-(1H-Phenanthro[9,10-d] imidazol-2-yl) benzaldehyde (P-1) was prepared as a new ratiometric optical probe for hydrogen sulfite. Upon the addition of HSO3-, it displayed large emission wavelength shift (Delta lambda = 120 nm) and the detection limit was determined to be as low as 2 mu M. In addition to its high selectivity for hydrogen sulfite rather than other common anions, P-1 was successfully applied to the detection of hydrogen sulfite in HeLa cells with ratiometric fluorescent methods. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：274 / 280

页数：7

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