Synthesis of Oxovanadium(IV) Complexes with Tetraaza Coordinating Ligands

被引：4

作者：

Singh, Sanjay ^{[3
]}

Yadav, Hardeo S. ^{[2
]}

Yadava, Ashok Kumar ^{[2
]}

Rao, Devendra Pratap ^{[1
]}

机构：

[1] DAV Postgrad Coll, Dept Chem, Kanpur 208001, Uttar Pradesh, India

[2] NE Reg Inst Sci & Technol NERIST, Dept Chem, Nirjuli 791109, Arunachal Prade, India

[3] MGPG Coll, Dept Chem, Gorakhpur 273001, Uttar Pradesh, India

来源：

JOURNAL OF CHEMISTRY | 2013年 / 2013卷

关键词：

BASE COMPLEXES; REACTIVITY; HYDRAZONES; VANADIUM;

D O I：

10.1155/2013/947325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxovanadium(IV) complexes of the type [VO(mac)]SO4 (where mac = tetraaza macrocyclic ligands derived by condensation of thenil with 1,4-diaminobenzene or 3,4-diaminopyridine and their reaction with beta-diketones) have been prepared using vanadyl ion as kinetic template. The prepared macrocyclic complexes were characterized by elemental analyses, molar conductance, magnetic moments, and infrared, electronic, and electron spin resonance data. From the spectroscopic studies, five-coordinate square-pyramid geometry for he VO2+ complexes have been proposed wherein derived ligands act as tetradentate chelating agents.

引用

页数：5

共 50 条

[21] Synthesis, Characterization and Antimicrobial Activity of Oxovanadium(IV) Complexes of Schiff Base Hydrazones Containing Quinoxaline Moiety [J].

Lakshmi, P. V. Anantha ;

Satyanarayana, T. ;

Reddy, P. Saritha .

CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (04) :935-940

[22] Synthesis and structural characterization of oxovanadium(V) complexes with mixed tridentate benzohydrazone and bidentate no ligands [J].

Sheng, G. H. ;

Han, Y. W. ;

Xu, Y. ;

Hu, X. M. ;

You, Z. L. ;

Zhu, H. L. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2015, 41 (08) :496-502

[23] Synthesis, structure and solution chemistry of quaternary oxovanadium(V) complexes incorporating hydrazone ligands [J].

Mondal, Bipul ;

Drew, Michael G. B. ;

Ghosh, Tapas .

INORGANICA CHIMICA ACTA, 2009, 362 (09) :3303-3308

[24] Novel oxovanadium(IV) complexes with 4-acyl pyrazolone ligands: synthesis, crystal structure and catalytic activity towards the oxidation of benzylic alcohols [J].

Parihar, Sanjay ;

Jadeja, R. N. ;

Gupta, Vivek K. .

RSC ADVANCES, 2014, 4 (20) :10295-10302

[25] Synthesis, electrochemical and antimicrobial studies of mono and binuclear iron(III) and oxovanadium(IV) complexes of [ONO] donor tridentate Schiff-base ligands [J].

Bhattacharjee, Chira R. ;

Goswami, Pankaj ;

Sengupta, Mahuya .

JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (22) :3969-3980

[26] Leishmanicidal activity of polysaccharides and their oxovanadium(IV/V) complexes [J].

do Amaral, Alex Evangelista ;

Oliveira Petkowicz, Carmen Lucia ;

Ramalho Merce, Ana Lucia ;

Iacomini, Marcelo ;

Martinez, Glaucia Regina ;

Merlin Rocha, Maria Eliane ;

Suter Correia Cadena, Silvia Maria ;

Noleto, Guilhermina Rodrigues .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2015, 90 :732-741

[27] Spectroscopic Characterization of Some Oxovanadium(IV, V) Complexes [J].

Kumar, Reetesh ;

Singh, Puja ;

Kumar, Umesh ;

Singh, S. Suman ;

Saha, A. K. ;

Sharma, Shivadhar .

ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (16) :5298-5300

[28] Synthesis, Characterization and DNA Interaction Study of a New Oxovanadium (IV) Complex Containing Acetylacetone and Dicyandiamide as Ligands [J].

Devi, R. K. Bindiya ;

Devi, S. Pramodini ;

Singh, R. K. Hemakumar .

SPECTROSCOPY LETTERS, 2012, 45 (02) :93-103

[29] Two New Oxovanadium(V) Complexes With Hydrazone Ligands as Insulin Mimetics: Synthesis and Crystal Structures [J].

Hang, Zhi-Xi ;

Wang, Xing-Wen ;

Dong, Bo .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (10) :1351-1355

[30] Synthesis and characterization of novel oxovanadium(IV) complexes with 4-acyl-5-pyrazolone donor ligands: Evaluation of their catalytic activity for the oxidation of styrene derivatives [J].

Marchetti, Fabio ;

Pettinari, Claudio ;

Di Nicola, Corrado ;

Pettinari, Riccardo ;

Crispini, Alessandra ;

Crucianelli, Marcello ;

Di Giuseppe, Andrea .

APPLIED CATALYSIS A-GENERAL, 2010, 378 (02) :211-220

← 1 2 3 4 5 →