Laccase-catalyzed oxidative phenolic coupling of vanillidene derivatives

被引:50
作者
Constantin, Mihaela-Anca [1 ]
Conrad, Juergen [1 ]
Beifuss, Uwe [1 ]
机构
[1] Univ Hohenheim, Inst Chem, Bioorgan Chem, D-70599 Stuttgart, Germany
关键词
FERULIC ACID DEHYDRODIMERS; DOMINO REACTIONS; RELATIVE CONFIGURATION; BIOLOGICAL EVALUATION; MEDIATED OXIDATION; GREEN CHEMISTRY; IDENTIFICATION; DIMERIZATION; O-2; PRODUCTS;
D O I
10.1039/c2gc35848d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The laccase-catalyzed oxidative phenolic coupling of vanillidene derivatives using aerial oxygen as the oxidant has been developed. Depending on the substitution pattern of the vanillidene double bond of the substrate, either dilactones, dihydrobenzo[b]furans or biphenyls are formed.
引用
收藏
页码:2375 / 2379
页数:5
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