A simple quinoline derivatized thiosemicarbazone as a colorimetic and fluorescent sensor for relay recognition of Cu2+ and sulfide in aqueous solution

被引：68

作者：

Tang, Lijun ^{[1
]}

Zhou, Pei ^{[1
]}

Zhang, Qiang ^{[1
]}

Huang, Zhenlong ^{[1
]}

Zhao, Jia ^{[1
]}

Cai, Mingjun ^{[1
]}

机构：

[1] Bohai Univ, Dept Chem, Liaoning Prov Key Lab Synth & Applicat Funct Cpds, Jinzhou 121013, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷

关键词：

Copper detection; Sulfide recognition; Fluorescence; Thiosemicarbazide; SEQUENTIAL RECOGNITION; ZINC IONS; TURN-ON; COPPER; ANION; CHEMOSENSOR; 8-HYDROXYQUINOLINE; COMPLEXES; PROBE; WATER;

D O I：

10.1016/j.inoche.2013.08.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new quinoline derivatized thiosemicarbazone (1) was designed and synthesized as a colorimetric and fluorescent sensor. Sensor 1 displays highly selective and sensitive recognition to Cu2+ in aqueous solution (1% DMSO, HEPES 20 mM, pH = 7.4) via significant color and fluorescence changes. The on-site generated 1-Cu2+ complex exhibits high selectivity toward S2- over other anions and thiol-containing amino acids. The Cu2+ and S2- recognition processes are quick and reversible. Thus, rapid and highly selective relay recognition of Cu2+ and S2- by sensor 1 in aqueous solution has been achieved. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：100 / 104

页数：5

共 50 条

[1] A highly sensitive and selective fluorescent sensor for the determination of copper(II) based on a schiff base
Aksuner, Nur
Henden, Emuer
Yilmaz, Ibrahim
Cukurovali, Alaaddin
[J]. DYES AND PIGMENTS, 2009, 83 (02) : 211 - 217
[2] [Anonymous], 1981, HYDROGEN SULFIDE ENV
[3] Neurodegenerative diseases and oxidative stress
Barnham, KJ
Masters, CL
Bush, AI
[J]. NATURE REVIEWS DRUG DISCOVERY, 2004, 3 (03) : 205 - 214
[4] Oxidative cyclization of thiosemicarbazone: an optical and turn-on fluorescent chemodosimeter for Cu(II)
Basu, Arghya
Das, Gopal
[J]. DALTON TRANSACTIONS, 2011, 40 (12) : 2837 - 2843
[5] A Fluorescent Dissymmetric Thiosemicarbazone Ligand Containing a Hydrazonequinoline Arm and Its Complexes with Cadmium and Mercury
Calatayud, David G.
Lopez-Torres, Elena
Antonia Mendiola, M.
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (01) : 80 - 90
[6] A Near-Infrared Fluorescence Turn-On Sensor for Sulfide Anions
Cao, Xiaowei
Lin, Weiying
He, Longwei
[J]. ORGANIC LETTERS, 2011, 13 (17) : 4716 - 4719
[7] Cyclopalladated complexes containing tridentate thiosemicarbazone ligands of biological significance: Synthesis, structure and antimalarial activity
Chellan, Prinessa
Nasser, Shereen
Vivas, Livia
Chibale, Kelly
Smith, Gregory S.
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (19-20) : 2225 - 2232
[8] Fluorescent Chemosensors Based on Spiroring-Opening of Xanthenes and Related Derivatives
Chen, Xiaoqiang
Pradhan, Tuhin
Wang, Fang
Kim, Jong Seung
Yoon, Juyoung
[J]. CHEMICAL REVIEWS, 2012, 112 (03) : 1910 - 1956
[9] Sulfide-selective chemosignaling by a Cu2+ complex of dipicolylamine appended fluorescein
Choi, Myung Gil
Cha, Sunyoung
Lee, Haekyung
Jeon, Hye Lim
Chang, Suk-Kyu
[J]. CHEMICAL COMMUNICATIONS, 2009, (47) : 7390 - 7392
[10] Quinoline group based fluorescent sensor for detecting zinc ions in aqueous media and its logic gate behaviour
Dong, Zhengping
Guo, Yueping
Tian, Xin
Ma, Jiantai
[J]. JOURNAL OF LUMINESCENCE, 2013, 134 : 635 - 639

← 1 2 3 4 5 →