Self-assembly of monopyrazolylporphyrins by hydrogen bonding in solution

被引：54

作者：

Ikeda, C ^{[1
]}

Nagahara, N ^{[1
]}

Motegi, E ^{[1
]}

Yoshioka, N ^{[1
]}

Inoue, H ^{[1
]}

机构：

[1] Keio Univ, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904513i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-associated structures of two noble meso-(monopyrazolyltritolyl)porphyrins synthesized via their NH-protected precursors have been studied by H-1 NMR, FT-IR and ESI MS measurements; meso-(pyrazol-4-yl)porphyrin and meso-(3,5-dimethylpyrazol-4-yl)porphyrin form a dimer and a tetramer, respectively, in solution due to intermolecular hydrogen bonding between pyrazole units.

引用

页码：1759 / 1760

页数：2

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