Potential of High-Stability Perovskite Solar Cells for Low-Intensity-Low-Temperature (LILT) Outer Planetary Space Missions

被引:37
作者
Brown, C. R. [1 ]
Eperon, G. E. [2 ,3 ,4 ]
Whiteside, V. R. [1 ]
Sellers, I. R. [1 ]
机构
[1] Univ Oklahoma, Homer L Dodge Dept Phys & Astron, 440 W Brooks St, Norman, OK 73019 USA
[2] Cavendish Lab, J J Thomson Ave, Cambridge CB3 0HE, England
[3] Univ Washingtion, Dept Chem, Seattle, WA 98195 USA
[4] Natl Renewable Energy Lab, Golden, CO 80401 USA
基金
欧盟地平线“2020”;
关键词
perovskite; solar cell; mixed cation; phase transition; LILT; space; barrier; HYSTERESIS; TOLERANCE; BEHAVIOR;
D O I
10.1021/acsaem.8b01882
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mixed-cation-based perovskite solar cells are investigated under conditions consistent with those found in orbit around Mars, Jupiter, and Saturn. Temperature dependent photoluminescence spectra show no evidence of a phase change demonstrating the stability of these systems. At low temperature, a barrier that impedes current flow and reduces the fill factor is apparent in the operation of the solar cell, particularly at 1 sun AM0. However, under low intensity and low temperature, where thermionic emission limits the carrier extraction, the fill factor and efficiency are recovered demonstrating the promise of these systems for deep space missions.
引用
收藏
页码:814 / 821
页数:15
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