Synthesis of Biodegradable Polymers: A Review on the Use of Schiff-Base Metal Complexes as Catalysts for the Ring Opening Polymerization (ROP) of Cyclic Esters

被引：90
作者：
Santoro, Orlando [1 ]
Zhang, Xin [1 ]
Redshaw, Carl [1 ]
机构：
[1] Univ Hull, Dept Chem & Biochem, Plast Collab, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England
来源：
CATALYSTS | 2020年 / 10卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
Schiff-base; biodegradable polymers; polyesters; ROP; cyclic esters; lactones; EPSILON-CAPROLACTONE; ALUMINUM COMPLEXES; L-LACTIDE; RAC-LACTIDE; STEREOSELECTIVE POLYMERIZATION; ALKOXIDE COMPLEXES; LIGAND SYNTHESIS; STRUCTURAL-CHARACTERIZATION; OLEFIN POLYMERIZATION; EFFICIENT CATALYST;
D O I：
10.3390/catal10070800
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The synthesis and structure of the metal complexes, as well as all aspects concerning the polymerization process and the characteristics of the polymers formed, will be discussed.
引用
收藏
页码：1 / 49
页数：48
相关论文
共 50 条
  • [41] Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures
    Thomas, Christophe M.
    CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 165 - 173
  • [42] Use of samarium(III)-amino acid complexes as initiators of ring-opening polymerization of cyclic esters
    Medina, Dimas A.
    Contreras, Jesus M.
    Lopez-Carrasquero, Francisco J.
    Cardozo, Eduardo J.
    Contreras, Ricardo R.
    POLYMER BULLETIN, 2018, 75 (03) : 1253 - 1263
  • [43] Quinolyl/pyridyl-amino Li complexes as dual catalysts for the ring-opening polymerization of cyclic esters and degradation toward a circular economy approach
    Lin, Jian
    Wang, Peng
    Fan, Lei
    Xiao, Tian
    Cheng, Jianhua
    Chen, Xia
    POLYMER, 2023, 285
  • [44] Ring-opening polymerization of cyclic esters by phenoxy-thioether complexes derived from biocompatible metals
    Pilone, Alessia
    Lamberti, Marina
    Mazzeo, Mina
    Milione, Stefano
    Pellecchia, Claudio
    DALTON TRANSACTIONS, 2013, 42 (36) : 13036 - 13047
  • [45] Copper(II) complexes with imino phenoxide ligands: synthesis, characterization, and their application as catalysts for the ring-opening polymerization of rac-lactide
    Mandal, Mrinmay
    Oppelt, Kerstin
    List, Manuela
    Teasdale, Ian
    Chakraborty, Debashis
    Monkowius, Uwe
    MONATSHEFTE FUR CHEMIE, 2016, 147 (11): : 1883 - 1892
  • [46] Ring-opening polymerization of lactide using salen-aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine
    Cui, Yuan
    Li, Dongni
    Gao, Bo
    Zhou, Yuqi
    Chen, Li
    Qiu, Baoguo
    Li, Yanhui
    Duan, Qian
    Hu, Ninghai
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (04) : 656 - 667
  • [47] Use of heterometallic alkali metal-magnesium aryloxides in ring-opening polymerization of cyclic esters
    Petrus, Rafal
    Lis, Tadeusz
    Kowalinski, Adrian
    DALTON TRANSACTIONS, 2022, 51 (23) : 9144 - 9158
  • [48] Synthesis and characterization of benzoxazine-functionalized amine bridged bis(phenolate) lanthanide complexes and their application in the ring-opening polymerization of cyclic esters
    Liang, Zhenhua
    Ni, Xufeng
    Li, Xue
    Shen, Zhiquan
    DALTON TRANSACTIONS, 2012, 41 (09) : 2812 - 2819
  • [49] Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters
    Shen, Yong
    Li, Zhi-bo
    ACTA POLYMERICA SINICA, 2020, 51 (08): : 777 - 790
  • [50] Well-Controlled Ring-Opening Polymerization of Cyclic Esters Catalyzed by Aluminum Amido Complexes: Kinetics and Mechanism
    Liu, Junpeng
    Ma, Haiyan
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2014, 52 (21) : 3096 - 3106
12345