Synthesis of Biodegradable Polymers: A Review on the Use of Schiff-Base Metal Complexes as Catalysts for the Ring Opening Polymerization (ROP) of Cyclic Esters

被引：90
作者：
Santoro, Orlando [1 ]
Zhang, Xin [1 ]
Redshaw, Carl [1 ]
机构：
[1] Univ Hull, Dept Chem & Biochem, Plast Collab, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England
来源：
CATALYSTS | 2020年 / 10卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
Schiff-base; biodegradable polymers; polyesters; ROP; cyclic esters; lactones; EPSILON-CAPROLACTONE; ALUMINUM COMPLEXES; L-LACTIDE; RAC-LACTIDE; STEREOSELECTIVE POLYMERIZATION; ALKOXIDE COMPLEXES; LIGAND SYNTHESIS; STRUCTURAL-CHARACTERIZATION; OLEFIN POLYMERIZATION; EFFICIENT CATALYST;
D O I：
10.3390/catal10070800
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The synthesis and structure of the metal complexes, as well as all aspects concerning the polymerization process and the characteristics of the polymers formed, will be discussed.
引用
收藏
页码：1 / 49
页数：48
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