Synthesis of Biodegradable Polymers: A Review on the Use of Schiff-Base Metal Complexes as Catalysts for the Ring Opening Polymerization (ROP) of Cyclic Esters

被引：90
作者：
Santoro, Orlando [1 ]
Zhang, Xin [1 ]
Redshaw, Carl [1 ]
机构：
[1] Univ Hull, Dept Chem & Biochem, Plast Collab, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England
来源：
CATALYSTS | 2020年 / 10卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
Schiff-base; biodegradable polymers; polyesters; ROP; cyclic esters; lactones; EPSILON-CAPROLACTONE; ALUMINUM COMPLEXES; L-LACTIDE; RAC-LACTIDE; STEREOSELECTIVE POLYMERIZATION; ALKOXIDE COMPLEXES; LIGAND SYNTHESIS; STRUCTURAL-CHARACTERIZATION; OLEFIN POLYMERIZATION; EFFICIENT CATALYST;
D O I：
10.3390/catal10070800
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The synthesis and structure of the metal complexes, as well as all aspects concerning the polymerization process and the characteristics of the polymers formed, will be discussed.
引用
收藏
页码：1 / 49
页数：48
相关论文
共 50 条
  • [21] Controlled ring-opening polymerization of cyclic esters with phosphoric acid as catalysts
    Zhou, Xi
    Hong, Liangzhi
    COLLOID AND POLYMER SCIENCE, 2013, 291 (09) : 2155 - 2162
  • [22] Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters
    Gao, Jiahao
    Zhu, Dongzhi
    Zhang, Wenjuan
    Solan, Gregory A.
    Ma, Yanping
    Sun, Wen-Hua
    INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (10) : 2619 - 2652
  • [23] Aluminum methyl and isopropoxide complexes with ketiminate ligands: Synthesis, structural characterization and ring-opening polymerization of cyclic esters
    Altaf, Cigdem Tuc
    Wang, Haobing
    Keram, Maryam
    Yang, Yang
    Ma, Haiyan
    POLYHEDRON, 2014, 81 : 11 - 20
  • [24] Controlled Ring-Opening Polymerization of ε-Caprolactone Catalyzed by a Rare Earth Schiff-Base Complex
    Ni Xufeng
    Zhu Weiwei
    Shen Zhiquan
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (08) : 965 - 971
  • [25] Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone
    Hu, Chen-Yang
    Duan, Ran-Long
    Yang, Jing-Wei
    Dong, Shu-Jun
    Sun, Zhi-Qiang
    Pang, Xuan
    Wang, Xian-Hong
    Chen, Xue-Si
    CHINESE JOURNAL OF POLYMER SCIENCE, 2018, 36 (10) : 1123 - 1128
  • [26] Ring-Opening Polymerization of Cyclic Ester Catalyzed by Metal Complexes Containing Phosphorus and Nitrogen Bonds
    Wang, Xing
    Xue, Xiaopan
    Jiang, Youshu
    Zhang, Wenjuan
    Ma, Yanping
    Sun, Wen-Hua
    PROGRESS IN CHEMISTRY, 2024, 36 (10) : 1425 - 1442
  • [27] Group 4 metal complexes containing the salalen ligands: Synthesis, structural characterization and studies on the ROP of cyclic esters
    Chakraborty, Debashis
    Rajashekhar, Bijja
    Mandal, Mrinmay
    Ramkumar, Venkatachalam
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 871 : 111 - 121
  • [28] Advanced Catalysts in Ring-Opening Polymerization of Cyclic Esters
    Wu, Jincai
    Chen, Hsuan-Ying
    Hormnirun, Pimpa
    FRONTIERS IN CHEMISTRY, 2019, 7
  • [29] Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides
    Sarazin, Yann
    Carpentier, Jean-Francois
    CHEMICAL REVIEWS, 2015, 115 (09) : 3564 - 3614
  • [30] Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates
    Dagorne, Samuel
    Normand, Mickael
    Kirillov, Evgeny
    Carpentier, Jean-Francois
    COORDINATION CHEMISTRY REVIEWS, 2013, 257 (11-12) : 1869 - 1886
12345