Triblock copolymers from lactide and telechelic poly(cyclohexene carbonate)

被引:113
作者
Kember, Michael R. [1 ]
Copley, James [1 ]
Buchard, Antoine [1 ]
Williams, Charlotte K. [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
基金
英国工程与自然科学研究理事会;
关键词
RING-OPENING POLYMERIZATION; CO2/PROPYLENE OXIDE COPOLYMERIZATION; ALDIMINE ZINC-COMPLEXES; PROPYLENE-OXIDE; CYCLOHEXENE OXIDE; ALTERNATING COPOLYMERIZATION; CO2/EPOXIDE COPOLYMERIZATION; POLY(PROPYLENE CARBONATE); RENEWABLE RESOURCES; SALEN COMPLEXES;
D O I
10.1039/c2py00543c
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The preparation of alpha,omega-hydroxy-telechelic poly(cyclohexene carbonate) from a dizinc catalyst is reported. The telechelic polymer, with an yttrium initiator, can be used to polymerize lactide, yielding new triblock copolymers, substantially derived from renewable resources.
引用
收藏
页码:1196 / 1201
页数:6
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