Volatility and Aging of Atmospheric Organic Aerosol

被引：78

作者：

Donahue, Neil M. ^{[1
]}

Robinson, Allen L. ^{[1
]}

Trump, Erica R. ^{[1
]}

Riipinen, Ilona ^{[1
,2
,3
]}

Kroll, Jesse H. ^{[4
]}

机构：

[1] Carnegie Mellon Univ, Ctr Atmospher Particle Studies, Pittsburgh, PA 15213 USA

[2] Stockholm Univ, Dept Appl Environm Sci, S-10691 Stockholm, Sweden

[3] Stockholm Univ, Bert Bolin Ctr Climate Res, S-10691 Stockholm, Sweden

[4] MIT, Dept Civil & Environm Engn, Cambridge, MA 02139 USA

来源：

ATMOSPHERIC AND AEROSOL CHEMISTRY | 2014年 / 339卷

基金：

美国国家科学基金会;

关键词：

Aerosols; Atmospheric Chemistry; Multiphase Chemistry; POLYCYCLIC AROMATIC-HYDROCARBONS; MASS ACCOMMODATION COEFFICIENT; MOTOR-VEHICLE EMISSIONS; FINE-PARTICLE MASS; GAS-PHASE; SOURCE APPORTIONMENT; TERPENE OZONOLYSIS; PARTICULATE MATTER; PHOTOCHEMICAL OXIDATION; TEMPERATURE-DEPENDENCE;

D O I：

10.1007/128_2012_355

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organic-aerosol phase partitioning (volatility) and oxidative aging are inextricably linked in the atmosphere because partitioning largely controls the rates and mechanisms of aging reactions as well as the actual amount of organic aerosol. Here we discuss those linkages, describing the basic theory of partitioning thermodynamics as well as the dynamics that may limit the approach to equilibrium under some conditions. We then discuss oxidative aging in three forms: homogeneous gas-phase oxidation, heterogeneous oxidation via uptake of gas-phase oxidants, and aqueous-phase oxidation. We present general scaling arguments to constrain the relative importance of these processes in the atmosphere, compared to each other and compared to the characteristic residence time of particles in the atmosphere.

引用

收藏

页码：97 / 143

页数：47

相关论文

共 179 条

[1] O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry [J].

Aiken, Allison C. ;

Decarlo, Peter F. ;

Kroll, Jesse H. ;

Worsnop, Douglas R. ;

Huffman, J. Alex ;

Docherty, Kenneth S. ;

Ulbrich, Ingrid M. ;

Mohr, Claudia ;

Kimmel, Joel R. ;

Sueper, Donna ;

Sun, Yele ;

Zhang, Qi ;

Trimborn, Achim ;

Northway, Megan ;

Ziemann, Paul J. ;

Canagaratna, Manjula R. ;

Onasch, Timothy B. ;

Alfarra, M. Rami ;

Prevot, Andre S. H. ;

Dommen, Josef ;

Duplissy, Jonathan ;

Metzger, Axel ;

Baltensperger, Urs ;

Jimenez, Jose L. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (12) :4478-4485

[2] Effects of reversible adsorption and Langmuir-Hinshelwood surface reactions on gas uptake by atmospheric particles [J].

Ammann, M ;

Pöschl, U ;

Rudich, Y .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (02) :351-356

[3] Aerosol volatility measurement using an improved thermodenuder: Application to secondary organic aerosol [J].

An, Woo Jin ;

Pathak, Ravi K. ;

Lee, Byong-Hyoek ;

Pandis, Spyros N. .

JOURNAL OF AEROSOL SCIENCE, 2007, 38 (03) :305-314

[4]

[Anonymous], 2006, ATMOS CHEM PHYS

[5] Modelling the formation of organic particles in the atmosphere [J].

Anttila, T ;

Kerminen, VM ;

Kulmala, M ;

Laaksonen, A ;

O'Dowd, CD .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2004, 4 :1071-1083

[6] Mixing and phase partitioning of primary and secondary organic aerosols [J].

Asa-Awuku, A. ;

Miracolo, M. A. ;

Kroll, J. H. ;

Robinson, A. L. ;

Donahue, N. M. .

GEOPHYSICAL RESEARCH LETTERS, 2009, 36

[7] Modelling the evolution of organic carbon during its gas-phase tropospheric oxidation: development of an explicit model based on a self generating approach [J].

Aumont, B ;

Szopa, S ;

Madronich, S .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2005, 5 :2497-2517

[8] Secondary organic aerosols from anthropogenic and biogenic precursors [J].

Baltensperger, U ;

Kalberer, M ;

Dommen, J ;

Paulsen, D ;

Alfarra, MR ;

Coe, H ;

Fisseha, R ;

Gascho, A ;

Gysel, M ;

Nyeki, S ;

Sax, M ;

Steinbacher, M ;

Prevot, ASH ;

Sjögren, S ;

Weingartner, E ;

Zenobi, R .

FARADAY DISCUSSIONS, 2005, 130 :265-278

[9] OH clock determination by proton transfer reaction mass spectrometry at an environmental chamber [J].

Barmet, P. ;

Dommen, J. ;

DeCarlo, P. F. ;

Tritscher, T. ;

Praplan, A. P. ;

Platt, S. M. ;

Prevot, A. S. H. ;

Donahue, N. M. ;

Baltensperger, U. .

ATMOSPHERIC MEASUREMENT TECHNIQUES, 2012, 5 (03) :647-656

[10] Application of the np plus mP modeling approach for simulating secondary organic particulate matter formation from α-pinene oxidation [J].

Barsanti, Kelley C. ;

Smith, James N. ;

Pankow, James F. .

ATMOSPHERIC ENVIRONMENT, 2011, 45 (37) :6812-6819

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