Van't Hoff analysis in chiral chromatography

被引：74
作者：
Asnin, Leonid D. [1 ]
Stepanova, Maria V. [1 ]
机构：
[1] Perm Natl Res Polytech Univ, Dept Chem & Biotechnol, Komsomolsky Al 29, Perm 614990, Russia
来源：
JOURNAL OF SEPARATION SCIENCE | 2018年 / 41卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
adsorption thermodynamics; chiral chromatography; Van't Hoff plot; PHASE LIQUID-CHROMATOGRAPHY; ENTHALPY-ENTROPY COMPENSATION; HOLD-UP VOLUME; HYDROPHOBIC INTERACTION CHROMATOGRAPHY; ISOTHERMAL TITRATION CALORIMETRY; GRAFTED ANTIBIOTIC EREMOMYCIN; AMINO-ACID ENANTIOMERS; ETHER STATIONARY-PHASE; MOBILE-PHASE; QUINIDINE-CARBAMATE;
D O I：
10.1002/jssc.201701264
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The present review discusses the theory and application of van't Hoff analysis in chiral chromatography, with main focus on liquid chromatography. The topics considered include the physical meaning of van't Hoff equation's parameters, interpretation of thermodynamic data in terms of retention and enantioseparation mechanisms, abnormal behavior of van't Hoff plots, and best practices to avoid biased results.
引用
收藏
页码：1319 / 1337
页数：19
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